A room temperature rechargeable Li2O-based lithium-air battery enabled by a solid electrolyte

被引：132

作者：

Kondori, Alireza ^{[1
]}

Esmaeilirad, Mohammadreza ^{[1
]}

Harzandi, Ahmad Mosen ^{[1
]}

Amine, Rachid ^{[2
]}

Saray, Mahmoud Tamadoni ^{[3
]}

Yu, Lei ^{[4
]}

Liu, Tongchao ^{[5
]}

Wen, Jianguo ^{[4
]}

Shan, Nannan ^{[2
,6
]}

Wang, Hsien-Hau ^{[2
]}

Ngo, Anh T. ^{[2
,6
]}

Redfern, Paul C. ^{[2
]}

Johnson, Christopher S. ^{[5
]}

Amine, Khalil ^{[5
,7
,8
]}

Shahbazian-Yassar, Reza ^{[3
]}

Curtiss, Larry A. ^{[2
]}

Asadi, Mohammad ^{[1
]}

机构：

[1] IIT, Dept Chem & Biol Engn, Chicago, IL 60616 USA

[2] Argonne Natl Lab, Mat Sci Div, Lemont, IL 60439 USA

[3] Univ Illinois, Dept Mech & Ind Engn, Chicago, IL 60607 USA

[4] Argonne Natl Lab, Ctr Nanoscale Mat, Lemont, IL 60439 USA

[5] Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA

[6] Univ Illinois, Dept Chem Engn, Chicago, IL 60607 USA

[7] Stanford Univ, Mat Sci & Engn, Stanford, CA 94305 USA

[8] Imam Abdulrahman Bin Faisal Univ IAU, Inst Res & Med Consultat IRMC, Dammam, Saudi Arabia

来源：

SCIENCE | 2023年 / 379卷 / 6631期

基金：

美国国家科学基金会;

关键词：

LONG CYCLE LIFE; HIGH-ENERGY-DENSITY; CHARGE-TRANSPORT; OXYGEN BATTERY; POLYMER ELECTROLYTES; IONIC-CONDUCTIVITY; STATE; SUPEROXIDE; COMPOSITE; PERFORMANCE;

D O I：

10.1126/science.abq1347

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

A lithium-air battery based on lithium oxide (Li2O) formation can theoretically deliver an energy density that is comparable to that of gasoline. Lithium oxide formation involves a four-electron reaction that is more difficult to achieve than the one-and two-electron reaction processes that result in lithium superoxide (LiO2) and lithium peroxide (Li2O2), respectively. By using a composite polymer electrolyte based on Li10GeP2S12 nanoparticles embedded in a modified polyethylene oxide polymer matrix, we found that Li2O is the main product in a room temperature solid-state lithium-air battery. The battery is rechargeable for 1000 cycles with a low polarization gap and can operate at high rates. The four-electron reaction is enabled by a mixed ion-electron-conducting discharge product and its interface with air.

引用

页码：499 / 504

页数：6

共 50 条

[1] A lithium-oxygen battery with a long cycle life in an air-like atmosphere
Asadi, Mohammad
Sayahpour, Baharak
Abbasi, Pedram
Ngo, Anh T.
Karis, Klas
Jokisaari, Jacob R.
Liu, Cong
Narayanan, Badri
Gerard, Marc
Yasaei, Poya
Hu, Xuan
Mukherjee, Arijita
Lau, Kah Chun
Assary, Rajeev S.
Khalili-Araghi, Fatemeh
Klie, Robert F.
Curtiss, Larry A.
Salehi-Khojin, Amin
[J]. NATURE, 2018, 555 (7697) : 502 - +
[2] CONDUCTIVITY AND TRANSFERENCE NUMBER MEASUREMENTS ON POLYMER ELECTROLYTES
BRUCE, PG
EVANS, J
VINCENT, CA
[J]. SOLID STATE IONICS, 1988, 28 : 918 - 922
[3] Determining and Minimizing Resistance for Ion Transport at the Polymer/Ceramic Electrolyte Interface
Chen, X. Chelsea
Liu, Xiaoming
Pandian, Amaresh Samuthira
Lou, Kun
Delnick, Frank M.
Dudney, Nancy J.
[J]. ACS ENERGY LETTERS, 2019, 4 (05) : 1080 - 1085
[4] Effects of Plasticizer Content and Ceramic Addition on Electrochemical Properties of Cross-Linked Polymer Electrolyte
Du, Zhijia
Chen, X. Chelsea
Sahore, Ritu
Wu, Xianyang
Li, Jianlin
Dudney, Nancy J.
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2021, 168 (05)
[5] Reactions in the Rechargeable Lithium-O2 Battery with Alkyl Carbonate Electrolytes
Freunberger, Stefan A.
Chen, Yuhui
Peng, Zhangquan
Griffin, John M.
Hardwick, Laurence J.
Barde, Fanny
Novak, Petr
Bruce, Peter G.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (20) : 8040 - 8047
[6] Ionic conductivity in crystalline polymer electrolytes
Gadjourova, Z
Andreev, YG
Tunstall, DP
Bruce, PG
[J]. NATURE, 2001, 412 (6846) : 520 - 523
[7] An amorphous LiO2-based Li-O2 battery with low overpotential and high rate capability
Gao, Rui
Liang, Xiu
Yin, Penggang
Wang, Junkai
Lee, Yu Lin
Hu, Zhongbo
Liu, Xiangfeng
[J]. NANO ENERGY, 2017, 41 : 535 - 542
[8] Rechargeable-battery chemistry based on lithium oxide growth through nitrate anion redox
Giordani, Vincent
Tozier, Dylan
Uddin, Jasim
Tan, Hongjin
Gallant, Betar M.
McCloskey, Bryan D.
Greer, Julia R.
Chase, Gregory, V
Addison, Dan
[J]. NATURE CHEMISTRY, 2019, 11 (12) : 1133 - 1138
[9] Study on lithium/air secondary batteries-Stability of NASICON-type lithium ion conducting glass-ceramics with water
Hasegawa, Satoshi
Imanishi, Nobuyuki
Zhang, Tao
Xie, Jian
Hirano, Atsushi
Takeda, Yasuo
Yamamoto, Osamu
[J]. JOURNAL OF POWER SOURCES, 2009, 189 (01) : 371 - 377
[10] Studies on Conductivity, Structural and Thermal Properties of PEO-LiTFSI Polymer Electrolytes doped with EMImTFSI Ionic Liquid
Hashim, N. H. A. M.
Subban, R. H. Y.
[J]. 3RD INTERNATIONAL SCIENCES, TECHNOLOGY & ENGINEERING CONFERENCE (ISTEC) 2018 - MATERIAL CHEMISTRY, 2018, 2031

← 1 2 3 4 5 →