Crystal structure and Hirshfeld surface analysis of (1H-imidazole-κN3)[N-(2-oxidobenzylidene)-tyrosinato-κ3O,N,O′]copper(II)

被引：2

作者：

Suzuki, Soma ^{[1
]}

Akiyama, Yukihito ^{[1
]}

Nakane, Daisuke ^{[1
]}

Akitsu, Takashiro ^{[1
]}

机构：

[1] Tokyo Univ Sci, Dept Chem, Fac Sci, 1-3 Kagurazaka,Shinjuku Ku, Tokyo 1628601, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷

关键词：

Schiff base complex; copper; amino acid; Hirshfeld analysis; crystal structure; COMPLEXES; COMPOSITES;

D O I：

10.1107/S2056989023004735

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title copper(II) complex, [Cu(C16H13NO4)(C3H4N2)], consists of a tridentate ligand synthesized from l-tyrosine and salicylaldehyde. One imidazole molecule is additionally coordinating to the copper(II) ion. The crystal structure features N-H center dot center dot center dot O, O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are from H center dot center dot center dot H (37.9%), C center dot center dot center dot H (28.2%) and O center dot center dot center dot H/H center dot center dot center dot O (21.2%) contacts.

引用

页码：596 / +

页数：8

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