Phosphine-catalysed transformations of ortho- and para-quinone methides

被引：11

作者：

Maestro, Aitor ^{[1
,2
]}

Zurro, Mercedes ^{[3
]}

机构：

[1] Univ Basque Country, Ctr Invest & Estudios Avanzados Lucio Lascaray, Dept Quim Organ 1, Fac Farm,UPV EHU, Paseo Univ 7, Vitoria 01006, Spain

[2] Karl Franzens Univ Graz, Inst Chem, NAWI Graz, Heinrichstr 28, A-8010 Graz, Austria

[3] Univ Alcala, Dept Quim Organ & Quim Inorgan, IRYCIS, Alcala De Henares 28805, Madrid, Spain

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 41期

关键词：

ASYMMETRIC 1,6-CONJUGATE ADDITION; RAUHUT-CURRIER REACTION; ENANTIOSELECTIVE SYNTHESIS; ACID; DIHYDROCOUMARINS; CONSTRUCTION; NAPHTHOLS; ADDITION/AROMATIZATION; CYCLOADDITIONS; 1,6-ADDITION;

D O I：

10.1039/d3ob01276j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organocatalytic methodologies for the derivatization of o-QM, p-QM and the analogous aza-QM have been recently developed and involve different catalytic systems such as phosphoric acids, thioureas, squaramides, NHC carbenes or chiral ammonium salts. Besides, phosphines, commonly used as ligands in metal-catalysed reactions, can be also used as organocatalysts. In this case, they are mainly involved as nucleophilic catalysts in reactions such as the Rauhut-Currier (RC) reaction. In this review, an analysis of the recent developments in racemic and enantioselective phosphine-catalysed transformations of o-QM, p-QM and aza-o-QM has been carried out.

引用

页码：8244 / 8258

页数：15

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