Wood-Poly(furfuryl Alcohol) Prepreg: A Novel, Ecofriendly Laminate Composite

被引:0
|
作者
Acosta, Andrey Pereira [1 ]
Esteves, Bruno [2 ]
Cruz, Joziel Aparecido da [1 ]
Aramburu, Arthur Behenck [1 ]
Kairyte, Agne [3 ]
Czlonka, Sylwia [4 ]
Ramos, Dionatan Orestes [5 ]
Goularte, Matheus de Paula [6 ]
Delucis, Rafael de Avila [6 ]
Gatto, Darci Alberto [6 ]
Amico, Sandro Campos [1 ]
机构
[1] Univ Fed Rio Grande do Sul, Postgrad Program Min Met & Mat Engn, BR-90040060 Porto Alegre, RS, Brazil
[2] Polytech Inst Viseu, Dept Wood Engn, Ave Cor Jose Maria Vale de Andrade, P-3504510 Viseu, Portugal
[3] Vilnius Gediminas Tech Univ, Lab Thermal Insulating Mat & Acoust, Inst Bldg Mat, Fac Civil Engn, Linkmenu St 28, LT-08217 Vilnius, Lithuania
[4] Lodz Univ Technol, Inst Polymer & Dye Technol, Fac Chem, Stefanowskiego 12-16, PL-90924 Lodz, Poland
[5] Univ Fed Rio Grande do Sul, Chem Engn, BR-90040060 Porto Alegre, RS, Brazil
[6] Univ Fed Pelotas, Postgrad Program Mat Sci & Engn, BR-96010150 Pelotas, RS, Brazil
关键词
vegetable fibers; wood laminates; ecofriendly resin; ecofriendly composite; pine wood; PHENOL-FORMALDEHYDE RESINS; MODEL-FREE KINETICS; MECHANICAL-PROPERTIES; THERMAL-DEGRADATION; WOOD; PATHWAYS; BEHAVIOR; LVL;
D O I
10.3390/ma16186237
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Prepregs are commonly fabricated with non-renewable petroleum-based materials. To reduce the impact of the manufacturing of these materials and to produce more sustainable prepregs, this research aims to manufacture poly(furfuryl alcohol)/wood veneer prepregs and their posterior molding in laminate composites. For this purpose, the vacuum infusion process was used to impregnate the wood veneers, and compression molding was applied to manufacture three- and four-layer laminate composites. Scanning electronic microscopy was used to evaluate the impregnation. the laminate manufacturing and differential scanning calorimetry were used to predict the shelf-life of the prepregs, Fourier-transform infrared was used to evaluate the induced hydrolysis resistance, and thermogravimetric analysis was used to determine the thermal degradation of the laminates. Moreover, water uptake and flexural, compressive, and tensile properties were evaluated. The kinetic models were effective and showed a shelf life for the laminates of approximately 30 days in storage at -7 degrees C, which is an interesting result for laminates with lignocellulosic materials. FTIR proved the laminates' excellent resistance to hydrolysis. The water absorption, thermal stability, and mechanical properties did not differ as the amount of wood veneer increased, but these results were up to similar to 40% higher compared with unidirectional wood laminates found in the literature, which is probably linked to the excellent interface observed with SEM.
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页数:16
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