nBu4N+[AgI(CF3)2]-: Trifluoromethylated Argentate Derived from Fluoroform and Its Reaction with (Hetero)Aryl Diazonium Salts

被引：4

作者：

Lu, Zehai ^{[1
]}

Wang, Linhua ^{[2
]}

Hughes, Matthew ^{[3
]}

Smith, Stephen ^{[4
]}

Shen, Qilong ^{[1
]}

机构：

[1] Univ Chinese Acad Sci, Shanghai Inst Organ Chem, Chinese Acad Sci, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China

[2] Syngenta Crop Protect, Prod Metab Analyt Sci, Greensboro, NC 27409 USA

[3] Syngenta Crop Protect, Mfg Ctr, Huddersfield HD2 1FF, England

[4] Syngenta Crop Protect, Jealotts Hill Int Res Ctr, Bracknell RG42 6EY, Berks, England

来源：

ORGANIC LETTERS | 2023年 / 26卷 / 14期

基金：

中国国家自然科学基金;

关键词：

SANDMEYER TRIFLUOROMETHYLATION; MEDIATED TRIFLUOROMETHYLATION; DIRECT CUPRATION; FLUORINE; CUCF3;

D O I：

10.1021/acs.orglett.3c02804

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The preparation of a well-defined trifluoromethylated argentate nBu(4)N(+)[Ag(CF3)(2)](-) 1 from fluoroform was described. The complex was stable in the solid state and in solution under an inert atmosphere. Treatment of a variety of (hetero)aryl diazonium tetrafluoroborates with nBu(4)N(+)[Ag(CF3)(2)](-) 1 generated trifluoromethylated (hetero)arenes in good to excellent yields. Preliminary experiments were conducted, and a reasonable mechanism of the reaction was proposed.

引用

页码：2773 / 2777

页数：5