Molecular confined synthesis of magnetic CoOx/Co/C hybrid catalyst for photocatalytic water oxidation and CO2 reduction

Photosynthesis [6CO2 + 12H2O -> (CH2O)6 + 6O 2 + 6H2O] in nature contains a light reaction process for oxygen evolution and a dark reaction process for carbon dioxide (CO2) reduction to carbohydrates, which is of great significance for the survival of living matter. Therefore, for simulating photosynthesis, it is desirable to design and fabricate a bifunctional catalyst for promoting photocatalytic water oxidation and CO2 reduction performances. Herein, a molecular confined synthesis strategy is reasonably proposed and applied, that is the bifunctional CoOx /Co/C-T ( T = 70 0, 80 0 and 900 degrees C) photocatalysts prepared by the pyrolysis of molecular Co-EDTA under N 2 and air atmosphere in turn. Among the prepared photocatalysts, the CoOx /Co/C-80 0 shows the best photocatalytic water oxidation activity with an oxygen yield of 51.2%. In addition, for CO2 reduction reaction, the CO evolution rate of 12.6 mu mol/h and selectivity of 75% can be achieved over this catalyst. The improved photocatalytic activities are attributed to the rapid electron transfer between the photosensitizer and the catalyst, which is strongly supported by the current density-voltage ( j-V ), steady-state and time-resolved photoluminescence spectra (PL). Overall, this work provides a reference for the preparation and optimization of photocatalysts with the capacity for water oxidation and CO2 reduction reactions.(c) 2023 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.