Enantioselective catalysts based on metal-organic framework-supported nucleotides

被引：0

作者：

Wang, Danyu ^{[1
,2
]}

Li, Zhe ^{[1
]}

Luo, Tian-Yi ^{[1
]}

Schmithorst, Michael B. ^{[3
]}

Park, Sunghwan ^{[1
,4
]}

Xu, Wenqian ^{[5
]}

Miao, Yurun ^{[1
]}

Gawande, Kaivalya ^{[6
]}

Tang, Chaoyun ^{[6
]}

Bukowski, Brandon C. ^{[2
]}

Chmelka, Bradley F. ^{[3
]}

Fairbrother, Howard ^{[7
]}

Kokkoli, Efrosini ^{[1
,2
]}

Tsapatsis, Michael ^{[1
,2
,8
]}

机构：

[1] Johns Hopkins Univ, Inst NanoBioTechnol, 3400 N Charles St, Baltimore, MD 21218 USA

[2] Johns Hopkins Univ, Dept Chem & Biomol Engn, 3400 N Charles St, Baltimore, MD 21218 USA

[3] Univ Calif Santa Barbara, Dept Chem Engn, Santa Barbara, CA 93106 USA

[4] Kyungpook Natl Univ, Sch Energy Mat & Chem Engn, 2559 Gyeongsang Daero, Sangju Si 37224, Gyeongsangbug D, South Korea

[5] Argonne Natl Lab, X Ray Sci Div, Adv Photon Source, Lemont, IL 60439 USA

[6] Univ Massachusetts Amherst, Dept Chem Engn, Amherst, MA 01003 USA

[7] Johns Hopkins Univ, Dept Chem, 3400 N Charles St, Baltimore, MD 21218 USA

[8] Johns Hopkins Univ, Appl Phys Lab, 11100 Johns Hopkins Rd, Laurel, MD 20723 USA

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2023年 / 360卷

关键词：

Metal-organic framework; Artificial metalloenzyme; Asymmetric catalysis; Heterogenous catalysis; DIELS-ALDER REACTION; AUXILIARY BASIS-SETS; ARTIFICIAL METALLOENZYMES; HYBRID CATALYSTS; DNA; WATER; SEPARATION; DESIGN; SITES;

D O I：

10.1016/j.micromeso.2023.112703

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Adenosine triphosphate (ATP) and other nucleotides can be irreversibly bound to the metal-organic framework (MOF) MIL-101(Cr). Analysis of X-ray diffraction data suggests that the location of the adsorbed ATP molecule is in proximity of the Cr3 clusters. Solid-state NMR and DFT calculations indicate that ATP is bound to MIL-101(Cr) through linkages of the terminal phosphate group with Cr(III) of the framework. In the presence of Cu(II) ions, the MOF-supported nucleotides can function as stable and reusable enantioselective heterogeneous catalysts for reactions like Diels-Alder and Michael addition. Compared to the corresponding homogeneous nucleotide-based artificial metalloenzymes (ArMs), the MOF-supported nucleotide-based ArMs exhibit significantly enhanced activity and selectivity in certain cases, demonstrating their potential as a new class of enantioselective heterogeneous catalysts.

引用

页数：12

共 78 条

[1] Synthesis of Metal-Organic Frameworks MIL-101(Cr)-NH2 Containing Phosphorous Acid Functional Groups: Application for the Synthesis of N-Amino-2-pyridone and Pyrano [2,3-c]pyrazole Derivatives via a Cooperative Vinylogous Anomeric-Based Oxidation
Babaee, Saeed
Zarei, Mahmoud
Sepehrmansourie, Hassan
Zolfigol, Mohammad Ali
Rostamnia, Sadegh
[J]. ACS OMEGA, 2020, 5 (12): : 6240 - 6249
[2] Postsynthetic Modification Switches an Achiral Framework to Catalytically Active Homochiral Metal-Organic Porous Materials
Banerjee, Mainak
Das, Sunirban
Yoon, Minyoung
Choi, Hee Jung
Hyun, Myung Ho
Park, Se Min
Seo, Gon
Kim, Kimoon
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (22) : 7524 - +
[3] Extendedtight-bindingquantum chemistry methods
Bannwarth, Christoph
Caldeweyher, Eike
Ehlert, Sebastian
Hansen, Andreas
Pracht, Philipp
Seibert, Jakob
Spicher, Sebastian
Grimme, Stefan
[J]. WILEY INTERDISCIPLINARY REVIEWS-COMPUTATIONAL MOLECULAR SCIENCE, 2021, 11 (02)
[4] GFN2-xTB-An Accurate and Broadly Parametrized Self-Consistent Tight-Binding Quantum Chemical Method with Multipole Electrostatics and Density-Dependent Dispersion Contributions
Bannwarth, Christoph
Ehlert, Sebastian
Grimme, Stefan
[J]. JOURNAL OF CHEMICAL THEORY AND COMPUTATION, 2019, 15 (03) : 1652 - 1671
[5] Exploring the Tunability of Trimetallic MOF Nodes for Partial Oxidation of Methane to Methanol
Barona, Melissa
Snurr, Randall Q.
[J]. ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (25) : 28217 - 28231
[6] Computational Predictions and Experimental Validation of Alkane Oxidative Dehydrogenation by Fe2M MOF Nodes
Barona, Melissa
Ahn, Sol
Morris, William
Hoover, William
Notestein, Justin M.
Farha, Omar K.
Snurr, Randall Q.
[J]. ACS CATALYSIS, 2020, 10 (02): : 1460 - 1469
[7] Distinct Catalytic Reactivity of Sn Substituted in Framework Locations and at Defect Grain Boundaries in Sn-Zeolites
Bates, Jason S.
Bukowski, Brandon C.
Harris, James W.
Greeley, Jeffrey
Gounder, Rajamani
[J]. ACS CATALYSIS, 2019, 9 (07) : 6146 - 6168
[8] DNA-cellulose: an economical, fully recyclable and highly effective chiral biomaterial for asymmetric catalysis
Benedetti, Erica
Duchemin, Nicolas
Bethge, Lucas
Vonhoff, Stefan
Klussmann, Sven
Vasseur, Jean-Jacques
Cossy, Janine
Smietana, Michael
Arseniyadis, Stellios
[J]. CHEMICAL COMMUNICATIONS, 2015, 51 (28) : 6076 - 6079
[9] DNA-based asymmetric catalysis: Sequence-dependent rate acceleration and enantioselectivity
Boersma, Arnold J.
Klijn, Jaap E.
Feringa, Ben L.
Roelfes, Gerard
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (35) : 11783 - 11790
[10] Boersma AJ, 2010, NAT CHEM, V2, P991, DOI [10.1038/NCHEM.819, 10.1038/nchem.819]

← 1 2 3 4 5 6 7 8 →