Effective surface passivation for stable and high-performance inverted CsPbI2Br perovskite solar cells with efficiency over 15%

被引:5
作者
Wang, Lang [1 ]
She, Xingchen [1 ]
Li, Wei [1 ]
Cao, Shihan [1 ]
Gong, Qiuyue [1 ]
Zhong, Zhenpeng [1 ]
Wang, Zhijun [3 ]
Li, Jie [1 ]
Liu, Hui [1 ]
Wang, Xiao [1 ]
Sun, Hui [1 ]
Yang, Dingyu [1 ]
Zhang, Jun [2 ]
Liu, Xin [1 ]
机构
[1] Chengdu Univ Informat Technol, Coll Optoelect Engn, Chengdu 610225, Peoples R China
[2] Shenzhen Bay Lab, Inst Syst & Phys Biol, Shenzhen 518055, Peoples R China
[3] Chengdu Univ, Inst Adv Study, Chengdu 610225, Peoples R China
基金
中国国家自然科学基金;
关键词
Inverted perovskite solar cell; CsPbI2Br; Defect passivation; Energy loss; High efficiency; IMPACT; FILMS;
D O I
10.1016/j.mtchem.2024.101980
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Developing high-efficiency and stable inverted CsPbI2Br perovskite solar cells is vitally urgent for their unique advantages of removing adverse dopants and compatible process with tandem cells in comparison with the regular. However, relatively low opening circuit voltage (V-oc) and limited moisture stability have lagged their progress far from the regular. Here, we propose an effective surface treatment strategy with high-temperature FABr treatment to address these issues. The induced ions exchange can not only adjust energy level, but also gift effective passivation. Meanwhile, the gradient distribution of FA(+) can accelerate the carriers transport to further suppress bulk recombination. Besides, the Br-rich surface and FA(+) substitution can isolate moisture erosions. As a result, the optimized devices show champion efficiency of 15.92% with V-oc of 1.223 V. In addition, the tolerance of humidity and operation get significant promotion: maintaining 91.7% efficiency after aged at RH 20% ambient condition for 1300 h and 81.8% via maximum power point tracking at 45 degrees C for 500 h in N-2. Furthermore, the unpackaged devices realize the rare reported air operational stability and, respectively, remain almost efficiency (98.9%) after operated under RH 35% for 600 min and 91.2% under RH 50% for 300 min.
引用
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页数:10
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