Controlled formation of multiple core-shell structures in metal-organic frame materials for efficient microwave absorption

The design of metal-organic frameworks (MOF) derived composites with multiple loss mechanisms and multiscale micro/nano structures is an important research direction of microwave absorbing materials. Herein, multi-scale bayberry-like Ni-MOF@N-doped carbon composites (Ni-MOF@N-C) are obtained by a MOF assisted strategy. By utilizing the special structure of MOF and regulating its composition, the effective improvement of Ni-MOF@N-C's microwave absorption performance has been achieved. The nanostructure on the surface of core-shell Ni-MOF@N-C can be regulated and N doping on carbon skeleton by adjusting the annealing temperature. The optimal reflection loss of Ni-MOF@N-C is -69.6 dB at 3 mm, and the widest effective absorption bandwidth is 6.8 GHz. This excellent performance can be attributed to the strong interface polarization caused by multiple core-shell structures, the defect and dipole polarization caused by N doping, and the magnetic loss caused by Ni. Meanwhile, the coupling of magnetic and dielectric properties enhances the impedance matching of Ni-MOF@N-C. The work proposes a particular idea of designing and synthesizing an applicable microwave absorption material that possesses excellent microwave absorption performance and promising application potential.