Electrocatalytic hydrogen evolution of manganese corrole

被引：27
作者：
Wan, Bei [1 ]
Cheng, Fan [1 ]
Lan, Jian [1 ]
Zhao, Yue [1 ]
Yang, Gang [1 ]
Sun, Yan-Mei [1 ]
Si, Li -Ping [2 ]
Liu, Hai -Yang [1 ]
机构：
[1] South China Univ Technol, Sch Chem & Chem Engn, Guangdong Prov Key Lab Fuel Cell Technol, Guangzhou 510641, Peoples R China
[2] Foshan Univ, Sch Mat Sci & Energy Engn, Foshan 528000, Peoples R China
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2023年 / 48卷 / 14期
基金：
中国国家自然科学基金;
关键词：
Manganese; Corrole; Electrocatalysis; Hydrogen evolution reaction; PROTON REDUCTION; ELECTRONIC-STRUCTURE; OXYGEN EVOLUTION; ACETIC-ACID; PORPHYRIN; COMPLEXES; CATALYST; SOLVENT; H-2; MODULATION;
D O I：
10.1016/j.ijhydene.2022.11.147
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A series of manganese corroles bearing different substituents had been prepared and characterized by UV-vis, 1H NMR, 19F NMR, HRMS and XPS. These manganese corrole complexes were applied to electrocatalytic hydrogen evolution reaction (HER) for the first time. The results showed that manganese corroles are effective catalysts for HER in DMF solvent by using acetic acid (AcOH), trifluoroacetic Acid (TFA) and p-toluenesulfonic acid (TsOH) proton sources, and strong acid leads to higher electrocatalytic activity. When using TsOH as proton source, protonation of corroles ligand may be involved in HER. The electrocatalytic HER activity can be improved by increasing the electron-withdrawing substituent of the corrole macrocycle in both organic and aqueous media. (c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：5506 / 5517
页数：12
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