Ionic liquid-functionalized halloysite as an efficient catalyst for the production of 5-hydroxymethylfurfural

被引：24

作者：

Sadjadi, Samahe ^{[1
]}

Abedian-Dehaghani, Neda ^{[2
]}

Zhong, Xuemin ^{[3
]}

Heravi, Majid M. ^{[2
]}

Yuan, Peng ^{[4
]}

机构：

[1] Iran Polymer & Petrochem Inst, Fac Petrochem, Gas Convers Dept, POB 14975112, Tehran, Iran

[2] Alzahra Univ, Sch Phys & Chem, Dept Chem, POB 1993891176,Vanak, Tehran, Iran

[3] Chinese Acad Sci, Guangzhou Inst Geochem, CAS Key Lab Mineral & Metallogeny, Guangdong Prov Key Lab Mineral Phys & Mat, Guangzhou 510640, Peoples R China

[4] Guangdong Univ Technol, Sch Environm Sci & Engn, Guangzhou 510006, Peoples R China

来源：

APPLIED CLAY SCIENCE | 2023年 / 237卷

基金：

中国国家自然科学基金; 美国国家科学基金会;

关键词：

5-Hydroxymethylfurfural; Heterogeneous catalyst; Ionic liquid; Halloysite; CARBONACEOUS CATALYST; FRUCTOSE; CONVERSION; DEHYDRATION; NANOTUBES; NANOPARTICLES; GLUCOSE; TRANSFORMATION; SUPPORT; 5-HMF;

D O I：

10.1016/j.clay.2023.106896

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three different acidic ionic liquids were covalently grafted on halloysite to give heterogeneous catalysts. The acidity of the catalysts was higher than halloysite and differed based on the nature of ionic liquid. Investigation of the catalytic activity of the catalysts for the synthesis of 5-hydroxymethylfurfural indicates that imidazolium-based ionic liquid showed the highest activity. Using this catalyst (30 wt%), 5-hydroxymethylfurfural was achieved from dehydration of fructose in 88% yield at 85 degrees C in 73 min. Furthermore, the catalyst was recyclable up to six runs with slight loss of activity. Comparison of the performance of the catalyst with halloysite-free counterpart confirmed the role of halloysite in improvement of the catalytic activity and recyclability.

引用

页数：9

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