THEORETICAL AND EXPERIMENTAL APPROACHES IN THE STUDY OF ELECTROCHEMICAL AND THERMODYNAMIC PROPERTIES OF POLYFUNCTIONAL ORGANIC COMPOUNDS IN LIQUID-PHASE AND HETEROPHASE SYSTEMS

被引：0

作者：

Bazanov, M. I. ^{[1
]}

Berezina, N. M. ^{[1
]}

Gridchin, S. N. ^{[1
]}

Krutova, O. N. ^{[1
]}

Gorboletova, G. G. ^{[1
]}

Bychkova, S. A. ^{[1
]}

Lytkin, A. I. ^{[1
]}

Chernyavskaya, N. V. ^{[1
]}

Chernikov, V. V. ^{[1
]}

Volkov, A. V. ^{[1
]}

机构：

[1] Ivanovo State Univ Chem & Technol, Dept Analyt & Organ Chem, Sheremetevsky Ave 7, Ivanovo 153000, Russia

来源：

IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA | 2023年 / 66卷 / 07期

关键词：

metalloporphyrins; aminocarbonic acids; complexes; cyclic voltammetry; electrocatalysis; calorimetry; potentiometry; equilibrium constant; enthalpy; entropy; COMPLEXES;

D O I：

10.6060/ivkkt.20236607.6839j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The publication reflects the experimental substantiation and fundamental development of some important ideas of the theory of the mutual influence of functional substitution in complex molecules of macrocyclic and chelating compounds on their coordination, solvation and redox properties, as well as the formation of algorithms for searching useful functions of these compounds. Researchers of the Analytical Chemistry Department of the Ivanovo State University of Chemistry and Technology have been studying the electrochemical and thermodynamic behavior of porphyrins, complexones, amino acids, peptides and the corresponding complexes with d-and f-metal ions, their influence on coordination, solvation and catalytic processes for a number of years. The results obtained together with the literature data are discussed in the review.

引用

页码：98 / 110

页数：13