One-step synthesis of MoS2/NiS heterostructures with a stable 1T phase for an efficient hydrogen evolution reaction

被引：9

作者：

Liu, Yanan ^{[1
]}

Li, Qiang ^{[1
]}

Zhu, Yue ^{[1
]}

Chen, Xiaoyu ^{[2
]}

Xue, Fan ^{[1
]}

Lyu, Mingxin ^{[1
]}

Li, Qiheng ^{[1
]}

Chen, Xin ^{[1
]}

Deng, Jinxia ^{[1
]}

Miao, Jun ^{[1
]}

Cao, Yili ^{[1
]}

Lin, Kun ^{[1
]}

Xing, Xianran ^{[1
]}

机构：

[1] Univ Sci & Technol Beijing, Inst Solid State Chem, Beijing 100083, Peoples R China

[2] Shenzhen Univ, Coll Mat Sci & Engn, Shenzhen 518071, Peoples R China

来源：

DALTON TRANSACTIONS | 2023年 / 52卷 / 25期

基金：

中国博士后科学基金; 国家重点研发计划; 中国国家自然科学基金;

关键词：

ACTIVE EDGE SITES; TRANSITION; ELECTROCATALYST; NANOSHEETS;

D O I：

10.1039/d3dt00838j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metallic phase (1T) MoS2 has been regarded as an ideal catalytic material for the hydrogen evolution reaction (HER) due to its high active site density and favorable electrical conductivity. However, the preparation of 1T-phase MoS2 samples requires tough reaction conditions and 1T-MoS2 has poor stability under alkaline conditions. In this work, 1T-MoS2/NiS heterostructure catalysts grown in situ on carbon cloth were prepared by a simple one-step hydrothermal method. The obtained MoS2/NiS/CC combines the advantages of high active site density and a self-supporting structure, achieving stable 77% metal phase (1T) MoS2. The combination of NiS and 1T-MoS2 enhances the intrinsic activity of MoS2 while the electrical conductivity is improved. These advantages enable the 1T-MoS2/NiS/CC electrocatalyst to have a low overpotential of 89 mV (@10 mA cm(-2)) and a small Tafel slope of 75 mV dec(-1) under alkaline conditions and provide a synthetic strategy of stable 1T-MoS2-based electrocatalysts for the HER by a heterogeneous structure.

引用

页码：8530 / 8535

页数：6

共 40 条

[11] Engineering interfacial structures to accelerate hydrogen evolution efficiency of MoS2 over a wide pH range [J].

Li, Shasha ;

Sirisomboonchai, Suchada ;

An, Xiaowei ;

Ma, Xuli ;

Li, Peng ;

Ling, Lixia ;

Hao, Xiaogang ;

Abudula, Abuliti ;

Guan, Guoqing .

NANOSCALE, 2020, 12 (12) :6810-6820

[12]

Lin YC, 2014, NAT NANOTECHNOL, V9, P391, DOI [10.1038/nnano.2014.64, 10.1038/NNANO.2014.64]

[13]

Liu H., 2020, CHEM ENG J, V397, P10274

[14] Heterogeneous Nanostructure Based on 1T-Phase MoS2 for Enhanced Electrocatalytic Hydrogen Evolution [J].

Liu, Zhipeng ;

Gao, Zhichao ;

Liu, Yuhua ;

Xia, Maosheng ;

Wang, Runwei ;

Li, Nan .

ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (30) :25291-25297

[15] Rich 1T-MoS2 Nanoflowers Decorated on Reduced Graphene Oxide Nanosheet for Ultra-Quick Zn2+ Storage [J].

Long, Fei ;

Shi, Junjie ;

Zhang, Qixiang ;

Liu, Zunyu ;

Hou, Yixin ;

Mao, Ke ;

Liu, Nishuang ;

Li, Luying ;

Long, Fei ;

Gao, Yihua .

BATTERIES & SUPERCAPS, 2022, 5 (08)

[16] Enhanced Hydrogen Evolution Catalysis from Chemically Exfoliated Metallic MoS2 Nanosheets [J].

Lukowski, Mark A. ;

Daniel, Andrew S. ;

Meng, Fei ;

Forticaux, Audrey ;

Li, Linsen ;

Jin, Song .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (28) :10274-10277

[17] Chemically activating MoS2 via spontaneous atomic palladium interfacial doping towards efficient hydrogen evolution [J].

Luo, Zhaoyan ;

Ouyang, Yixin ;

Zhang, Hao ;

Xiao, Meiling ;

Ge, Junjie ;

Jiang, Zheng ;

Wang, Jinlan ;

Tang, Daiming ;

Cao, Xinzhong ;

Liu, Changpeng ;

Xing, Wei .

NATURE COMMUNICATIONS, 2018, 9

[18] On hydrogen and hydrogen energy strategies I: current status and needs [J].

Midilli, A ;

Ay, M ;

Dincer, I ;

Rosen, MA .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2005, 9 (03) :255-271

[19] Interpretation of Ni2p XPS spectra of Ni conductors and Ni insulators [J].

Nesbitt, HW ;

Legrand, D ;

Bancroft, GM .

PHYSICS AND CHEMISTRY OF MINERALS, 2000, 27 (05) :357-366

[20] Single-atom cobalt array bound to distorted 1T MoS2 with ensemble effect for hydrogen evolution catalysis [J].

Qi, Kun ;

Cui, Xiaoqiang ;

Gu, Lin ;

Yu, Shansheng ;

Fan, Xiaofeng ;

Luo, Mingchuan ;

Xu, Shan ;

Li, Ningbo ;

Zheng, Lirong ;

Zhang, Qinghua ;

Ma, Jingyuan ;

Gong, Yue ;

Lv, Fan ;

Wang, Kai ;

Huang, Haihua ;

Zhang, Wei ;

Guo, Shaojun ;

Zheng, Weitao ;

Liu, Ping .

NATURE COMMUNICATIONS, 2019, 10 (1)

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