Adhesion Improvement of Bio-Based Epoxy in Environmentally Friendly and High-Performance Natural Fiber-Reinforced Composites

被引:17
作者
Kumar, Bijender [1 ]
Adil, Samia [1 ]
Kim, Jaehwan [1 ]
机构
[1] Inha Univ, Creat Res Ctr Nanocellulose Future Composites, Incheon 22212, South Korea
基金
新加坡国家研究基金会;
关键词
bio-based epoxy; composites; durability; mechanical properties; natural fibers; MECHANICAL-PROPERTIES; FACILE SYNTHESIS; FLAME-RETARDANT; BUILDING-BLOCK; VANILLIN; THERMOSETS; LIGNIN; VITRIMER; RESINS;
D O I
10.1002/mame.202300003
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Developing robust bio-based epoxy against petroleum-derived epoxy is necessary for environmentally friendly and high-performance natural fiber-reinforced composites. A bio-based vanillin epoxy (VE) is synthesized from the lignin-derived vanillin, and a thermoset resin is prepared after mixing it with a 4,4 '-diaminodiphenyl methane (DDM) hardener. Further, it is infused in high-cellulose-containing alkali-treated jute fiber (TJF) mats through a simple approach to enhance the adhesion between the VE-DDM and TJF. Bio-based VE-DDM resin shows better compatibility with TJF than petroleum-derived bisphenol A diglycidyl ether (DGEBA) epoxy. The bio-based VE-DDM/TJF composite demonstrates the T(g)is approximate to 165 degrees C, tensile strength is approximate to 83.12 +/- 3.80 MPa, and Young's modulus is approximate to 2.86 +/- 0.10 GPa with excellent flexural strength (138.72 +/- 3.81 MPa) and flexural modulus (8.01 +/- 0.11 GPa). It also shows merits regarding hydrophobicity, reduced water absorption ability, durability, and chemical resistance in an acidic medium. The natural fiber-reinforced VE composites pave the way to produce environmentally friendly and high-performance composites for structural applications.
引用
收藏
页数:12
相关论文
共 57 条
[41]   Fully bio-based cellulose nanofiber/epoxy composites with both sustainable production and selective matrix deconstruction towards infinite fiber recycling systems [J].
Subbotina, E. ;
Montanari, C. ;
Olsen, P. ;
Berglund, Lars A. .
JOURNAL OF MATERIALS CHEMISTRY A, 2022, 10 (02) :570-576
[42]   Mechanical Properties of Natural-Fiber-Reinforced Biobased Epoxy Resins Manufactured by Resin Infusion Process [J].
Torres-Arellano, Mauricio ;
Renteria-Rodriguez, Victoria ;
Franco-Urquiza, Edgar .
POLYMERS, 2020, 12 (12) :1-17
[43]   Recent advancement in the natural fiber polymer composites: A comprehensive review [J].
Vigneshwaran, S. ;
Sundarakannan, R. ;
John, K. M. ;
Johnson, R. Deepak Joel ;
Prasath, K. Arun ;
Ajith, S. ;
Arumugaprabu, V ;
Uthayakumar, M. .
JOURNAL OF CLEANER PRODUCTION, 2020, 277
[44]  
Wang BB, 2020, GREEN CHEM, V22, P1275, DOI [10.1039/c9gc04020j, 10.1039/C9GC04020J]
[45]   Facile in situ preparation of high-performance epoxy vitrimer from renewable resources and its application in nondestructive recyclable carbon fiber composite [J].
Wang, Sheng ;
Ma, Songqi ;
Li, Qiong ;
Xu, Xiwei ;
Wang, Binbo ;
Yuan, Wangchao ;
Zhou, Shenghua ;
You, Shusen ;
Zhu, Jin .
GREEN CHEMISTRY, 2019, 21 (06) :1484-1497
[46]   Vanillin-Derived High-Performance Flame Retardant Epoxy Resins: Facile Synthesis and Properties [J].
Wang, Sheng ;
Ma, Songqi ;
Xu, Chenxiang ;
Liu, Yuan ;
Dai, Jinyue ;
Wang, Zongbao ;
Liu, Xiaoqing ;
Chen, Jing ;
Shen, Xiaobin ;
Wei, Jingjing ;
Zhu, Jin .
MACROMOLECULES, 2017, 50 (05) :1892-1901
[47]   Characterization of KH-560-Modified Jute Fabric/Epoxy Laminated Composites: Surface Structure, and Thermal and Mechanical Properties [J].
Wang, Xue ;
Wang, Lihai ;
Ji, Wenwen ;
Hao, Quanling ;
Zhang, Guanghui ;
Meng, Qingkai .
POLYMERS, 2019, 11 (05)
[48]   Biobased Epoxy Synthesized from a Vanillin Derivative and Its Reinforcement Using Lignin-Containing Cellulose Nanofibrils [J].
Wang, Zhenyu ;
Gnanasekar, Pitchaimari ;
Nair, Sandeep Sudhakaran ;
Farnood, Ramin ;
Yi, Songlin ;
Yan, Ning .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (30) :11215-11223
[49]   New application for aromatic Schiff base: High efficient flame-retardant and anti-dripping action for polyesters [J].
Wu, Jia-Ning ;
Chen, Lin ;
Fu, Teng ;
Zhao, Hai-Bo ;
Guo, De-Ming ;
Wang, Xiu-Li ;
Wang, Yu-Zhong .
CHEMICAL ENGINEERING JOURNAL, 2018, 336 :622-632
[50]   Imine-functionalized biomass-derived dynamic covalent thermosets enabled by heat-induced self-crosslinking and reversible structures [J].
Xie, Weiqi ;
Huang, Shiwen ;
Liu, Shumei ;
Zhao, Jianqing .
CHEMICAL ENGINEERING JOURNAL, 2021, 404