Palladium-Catalyzed Oxidative Carbonylation of Diarylamines for the Synthesis of Acridone Derivatives

被引：0

作者：

Guo, Wenting ^{[1
]}

Wu, Wenting ^{[1
]}

Huang, Jiali ^{[1
]}

Zhang, Chengyan ^{[1
]}

Wang, Huiyan ^{[1
]}

Zhou, Hualan ^{[1
]}

Hu, Weiming ^{[1
]}

机构：

[1] Jiangsu Ocean Univ, Sch Environm & Chem Engn, Lianyungang 222005, Jiangsu, Peoples R China

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 13卷 / 04期

关键词：

Pd-catalyzed; Dual C-H activation; Carbonylation; Acridone derivatives; Safe CO source; MICROWAVE-ASSISTED SYNTHESIS; METAL-FREE SYNTHESIS; ONE-POT SYNTHESIS; C-BOND FORMATION; DIMETHYL-SULFOXIDE; MEDIATED SYNTHESIS; ARYL BROMIDES; H ACTIVATION; AMINOCARBONYLATION; ALCOHOLS;

D O I：

10.1002/ajoc.202300584

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Pd-catalyzed oxidative dual C-H carbonylation has been developed starting from commercially available diarylamines, in which the Cr(CO)6 served as a safe carbonyl source. This method provides a facile and atom-economic approach toward diversified acridone derivatives in moderate to good yields, which features with good functional group compatibility, operational safety and easy scale-up. A Pd-catalyzed oxidative dual C-H carbonylation has been developed starting from commercially available diarylamines, in which the Cr(CO)6 served as a safe carbonyl source. This method provides a facile and atom-economic approach toward diversified acridone derivatives in moderate to good yields, which features with good functional group compatibility, operational safety and easy scale-up.image

引用

页数：5

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