New Network Polymer Electrolytes Based on Ionic Liquid and SiO2 Nanoparticles for Energy Storage Systems

被引：8

作者：

Khatmullina, Kyunsylu G. ^{[1
,2
]}

Slesarenko, Nikita A. ^{[1
]}

Chernyak, Alexander V. ^{[1
,3
]}

Baymuratova, Guzaliya R. ^{[1
]}

Yudina, Alena V. ^{[1
]}

Berezin, Mikhail P. ^{[1
]}

Tulibaeva, Galiya Z. ^{[1
]}

Slesarenko, Anna A. ^{[1
]}

Shestakov, Alexander F. ^{[1
,4
]}

Yarmolenko, Olga V. ^{[1
]}

机构：

[1] RAS, Fed Res Ctr Problems Chem Phys & Med Chem, Chernogolovka 142432, Russia

[2] Natl Res Univ, Inst Energy Efficiency & Hydrogen Technol IEEHT, Moscow Power Engn Inst, Dept Chem & Electrochem Energy, Moscow 111250, Russia

[3] RAS, Inst Solid State Phys, Sci Ctr Chernogolovka, Chernogolovka 142432, Russia

[4] Moscow MV Lomonosov State Univ, Fac Fundamental Phys & Chem Engn, Moscow 119991, Russia

来源：

MEMBRANES | 2023年 / 13卷 / 06期

关键词：

nanocomposite polymer gel electrolytes; SiO2; nanoparticles; NMR with PFG; self-diffusion coefficients; ionic conductivity; solid-state lithium battery; solvate shell; quantum-chemical modeling; NANOCOMPOSITE; BATTERY; CONDUCTIVITY; DIFFUSION; SILICA; SALT;

D O I：

10.3390/membranes13060548

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Elementary processes of electro mass transfer in the nanocomposite polymer electrolyte system by pulse field gradient, spin echo NMR spectroscopy and the high-resolution NMR method together with electrochemical impedance spectroscopy are examined. The new nanocomposite polymer gel electrolytes consisted of polyethylene glycol diacrylate (PEGDA), salt LiBF4 and 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIBF4) and SiO2 nanoparticles. Kinetics of the PEGDA matrix formation was studied by isothermal calorimetry. The flexible polymer-ionic liquid films were studied by IRFT spectroscopy, differential scanning calorimetry and temperature gravimetric analysis. The total conductivity in these systems was about 10(-4) S cm(-1) (-40 & DEG;C), 10(-3) S cm(-1) (25 & DEG;C) and 10(-2) S cm(-1) (100 & DEG;C). The method of quantum-chemical modeling of the interaction of SiO2 nanoparticles with ions showed the advantage of the mixed adsorption process, in which a negatively charged surface layer is formed from Li+ BF4- ions on silicon dioxide particles and then from ions of the ionic liquid EMI+ BF4-. These electrolytes are promising for use both in lithium power sources and in supercapacitors. The paper shows preliminary tests of a lithium cell with an organic electrode based on a pentaazapentacene derivative for 110 charge-discharge cycles.

引用

页数：21

共 46 条

[1] Nanocomposites of Inorganic Oxides with Ionic Liquids. Synthesis, Properties, Application (Review) [J].

Agafonov, A. V. ;

Grishina, E. P. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 64 (13) :1641-1648

[2] An overview of the applications of ionic fluids and deep eutectic solvents enhanced by nanoparticles [J].

Bo, Liu ;

Zhang, Xiaojuan ;

Luo, Zhenmin ;

Saboori, Tabassom ;

Dehghan, Maziar ;

Ghasemizadeh, Mahsa ;

Karimi-Maleh, Hassan ;

Alagumalai, Avinash ;

Mahian, Omid .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2022, 147 (14) :7589-7601

[3] Review-Polymer Electrolytes for Rechargeable Batteries: From Nanocomposite to Nanohybrid [J].

Boaretto, Nicola ;

Meabe, Leire ;

Martinez-Ibanez, Maria ;

Armand, Michel ;

Zhang, Heng .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2020, 167 (07)

[4] Lithium-polymer battery with ionic liquid tethered nanoparticles incorporated P(VDF-HFP) nanocomposite gel polymer electrolyte [J].

Bose, Pallab ;

Deb, Debalina ;

Bhattacharya, Subhratanu .

ELECTROCHIMICA ACTA, 2019, 319 :753-765

[5] Ionogel Electrolytes for High-Performance Lithium Batteries: A Review [J].

Chen, Nan ;

Zhang, Haiqin ;

Li, Li ;

Chen, Renjie ;

Guo, Shaojun .

ADVANCED ENERGY MATERIALS, 2018, 8 (12)

[6] Silica gel solid nanocomposite electrolytes with interfacial conductivity promotion exceeding the bulk Li-ion conductivity of the ionic liquid electrolyte filler [J].

Chen, Xubin ;

Put, Brecht ;

Sagara, Akihiko ;

Gandrud, Knut ;

Murata, Mitsuhiro ;

Steele, Julian A. ;

Yabe, Hiroki ;

Hantschel, Thomas ;

Roeffaers, Maarten ;

Tomiyama, Morio ;

Arase, Hidekazu ;

Kaneko, Yukihiro ;

Shimada, Mikinari ;

Mees, Maarten ;

Vereecken, Philippe M. .

SCIENCE ADVANCES, 2020, 6 (02)

[7] Ionic liquid functionalized electrospun gel polymer electrolyte for use in a high-performance lithium metal battery [J].

Cheng, Yuanyuan ;

Zhang, Lan ;

Xu, Song ;

Zhang, Haitao ;

Ren, Baozeng ;

Li, Tao ;

Zhang, Suojiang .

JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (38) :18479-18487

[8] Influence of the reticular polymeric gel-electrolyte structure on ionic and molecular mobility of an electrolyte system salt-ionic liquid: LiBF4-1-ethyl-3-methylimidazolium tetrafluoroborate [J].

Chernyak, A. V. ;

Berezin, M. P. ;

Slesarenko, N. A. ;

Zabrodin, V. A. ;

Volkov, V. I. ;

Yudina, A. V. ;

Shuvalova, N. I. ;

Yarmolenko, O. V. .

RUSSIAN CHEMICAL BULLETIN, 2016, 65 (08) :2053-2058

[9] NMR study of the polyethylene glycol diacrylate-LiBF4-1-butyl-3-methylimidazolium tetrafluoroborate-propylene/ethylene carbonate electrolyte system [J].

Chernyak, A. V. ;

Yudina, A. V. ;

Yarmolenko, O. V. ;

Volkov, V. I. .

RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2015, 51 (05) :478-482

[10] Effect of the Solvate Environment of Lithium Cations on the Resistance of the Polymer Electrolyte/Electrode Interface in a Solid-State Lithium Battery [J].

Chernyak, Alexander, V ;

Slesarenko, Nikita A. ;

Slesarenko, Anna A. ;

Baymuratova, Guzaliya R. ;

Tulibaeva, Galiya Z. ;

Yudina, Alena, V ;

Volkov, Vitaly, I ;

Shestakov, Alexander F. ;

Yarmolenko, Olga, V .

MEMBRANES, 2022, 12 (11)

← 1 2 3 4 5 →