Selective control in the reductive amination of benzaldehyde towards corresponding amines over COF supported Pt, Pd, and Rh catalysts

被引：11

作者：

Wang, Nan ^{[1
,3
]}

Liu, Jianguo ^{[2
]}

Li, Xinjun ^{[3
]}

Ma, Longlong ^{[1
,2
]}

机构：

[1] Tianjin Univ, Sch Environm Sci & Engn, Tianjin 300350, Peoples R China

[2] Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China

[3] Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2023年 / 175卷

基金：

中国国家自然科学基金;

关键词：

Selective control; COF supported; Reductive amination; Pt; Pd; Rh metal promoter; COVALENT ORGANIC FRAMEWORK; ENANTIOSELECTIVE SYNTHESIS; MOLECULAR-HYDROGEN; SECONDARY-AMINES; AQUEOUS AMMONIA; NANOPARTICLES; FURFURYLAMINE; ALCOHOLS;

D O I：

10.1016/j.catcom.2023.106620

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Since selective control in catalytic reductive aminations of aldehyde for the synthesis of functional amines was highly valued, we developed three kinds of COFs supported catalysts (Pt/COF, Pd/COF, and Rh/COF) for selectively catalytic reductive amination of benzaldehyde. Results indicated that Pd/COF and Pt/COF exhibited good selectivity towards secondary amines with a 1.2/1 M proportion of aldehyde and ammonia, while Rh/COF catalyst can selectively convert benzaldehyde to secondary imine with an excellent yield of 90%. Furthermore, an improved yield of primary amine could be obtained over Rh/COF catalyst with a 1.2/60 M proportion of aldehyde and ammonia.

引用

页数：9

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