High efficient conversion of Cannabis sativa L. biomass into bioenergy by using green tungsten oxide nano-catalyst towards carbon neutrality

被引:44
作者
Abbasi, Tehreem Usman [1 ]
Ahmad, Mushtaq [2 ,8 ]
Asma, Maliha [1 ]
Rozina [2 ]
Munir, Mamoona [2 ,3 ]
Zafar, Muhammad [2 ]
Katubi, Khadijah Mohammedsaleh [4 ]
Alsaiari, Norah Salem [4 ]
Yahya, Adel E. M. [5 ]
Mubashir, Muhammad [6 ]
Chuah, Lai Fatt [7 ,8 ]
Bokhari, Awais [8 ]
机构
[1] Int Islamic Univ, Dept Environm Sci, Islamabad, Pakistan
[2] Quaid I Azam Univ, Dept Plant Sci, Islamabad 45320, Pakistan
[3] Rawalpindi Women Univ, Dept Bot, Rawalpindi, Pakistan
[4] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Dept Chem, POB 84428, Riyadh 11671, Saudi Arabia
[5] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
[6] Asia Pacific Univ Technol & Innovat, Sch Engn, Dept Petr Engn, Kuala Lumpur 57000, Malaysia
[7] Univ Malaysia Terengganu, Fac Maritime Studies, Terengganu, Malaysia
[8] Brno Univ Technol, Fac Mech Engn, NETME Ctr, Sustainable Proc Integrat Lab,SPIL, VUT Brno Tech 2896-2, Brno 61600, Czech Republic
关键词
Cannabis sativa; Non-edible seed oil; Biodiesel; Green synthesis; Tungsten oxide nanoparticles; WASTE COOKING OIL; RUBBER SEED OIL; BIODIESEL PRODUCTION; METHYL-ESTERS; TRANSESTERIFICATION;
D O I
10.1016/j.fuel.2022.126796
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Current study focuses on the utilization of non-edible oil seeds of Cannabis sativa as an economical feedstock for synthesizing high quality biodiesel using novel, green and extremely reactive tungsten oxide (WO3) nano catalyst. The as synthesized green nanoparticles (NPs) were examined using Fourier-transform infrared spec-troscopy (FT-IR), X-ray Diffraction (XRD), energy diffraction X-ray (EDX) and scanning electron microscopy (SEM). Results showed that WO3 has spherical crystal structure with a diameter of 45 nm. Highest biodiesel yield (91 wt%) was achieved under dynamic conditions i.e., 2 wt% catalyst, 1:7 oil to methanol molar ratio, 80 degrees C reaction temperature for 120 min. The reaction conditions were optimized via Response Surface Methodology. WO3 NPs showed catalytic stability up to five rounds. The fuel characteristics of biodiesel met the values set by international standards. Non-edible Cannabis sativa seed oil and novel green WO3 nano-catalyst are economical choices to assist the sustainable growth of biodiesel industry.
引用
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页数:10
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