A novel multistage forming process with intermediate annealing for PEMFC titanium bipolar plates with fine flow channels

被引:9
作者
Zhang, Xianglu [1 ]
Guo, Nan [1 ]
Hou, Zeran [1 ]
Chen, Bo [1 ]
Yang, Daijun [2 ,3 ]
Min, Junying [1 ]
Ming, Pingwen [2 ,3 ]
Zhang, Cunman [2 ,3 ]
机构
[1] Tongji Univ, Sch Mech Engn, Shanghai 201804, Peoples R China
[2] Tongji Univ, Clean Energy Automot Engn Ctr, Shanghai 201804, Peoples R China
[3] Tongji Univ, Sch Automot Studies, Shanghai 201804, Peoples R China
关键词
Preform annealing process; Formability; Microstructural evolution; Titanium bipolar plate; Flow channel; MICRO-CHANNELS; FUEL-CELLS; FABRICATION; SIMULATION; SHEET;
D O I
10.1016/j.ijhydene.2023.10.285
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, the preform annealing process is first introduced to improve the formability of titanium bipolar plates, comprising preforming, intermediate annealing and final shaping stages. Heat-assisted two-stage tensile tests are conducted to understand the mechanical properties evolution and the underlying mechanisms. Optimal annealing at 600 degrees C enables plastic recovery and recrystallization in pre-deformed titanium sheets without significant grain growth, leading to an enhancement in both work hardening capacity and forming limits. Feasibility of applying preform annealing to titanium bipolar plates is verified with three case studies, demonstrating its effectiveness in enhancing thickness uniformity and forming limits of microchannels compared to conventional room-temperature stamping. This facilitates the fabrication of titanium bipolar plates with narrow pitch (1.2 mm), high aspect ratio (0.79) and narrow wall angle (5 degrees). Hence, preform annealing provides a potential solution for fabricating titanium bipolar plates with fine flow channels for high-power proton exchange membrane fuel cells.
引用
收藏
页码:1362 / 1372
页数:11
相关论文
共 43 条
[1]   Micro-roll forming of stainless steel bipolar plates for fuel cells [J].
Abeyrathna, Buddhika ;
Zhang, Peng ;
Pereira, Michael P. ;
Wilkosz, Daniel ;
Weiss, Matthias .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (07) :3861-3875
[2]   Study of thickness distribution and dimensional accuracy of stamped metallic bipolar plates [J].
Barzegari, Mohammad M. ;
Khatir, Farzad Ahmadi .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (59) :31360-31371
[3]   Review of materials and characterization methods for polymer electrolyte fuel cell flow-field plates [J].
Brett, Daniel J. L. ;
Brandon, Nigel P. .
JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY, 2007, 4 (01) :29-44
[4]   Development of titanium bipolar plates fabricated by additive manufacturing for PEM fuel cells in electric vehicles [J].
Celik, Selahattin ;
Timurkutluk, Bora ;
Aydin, Ugur ;
Yagiz, Mikail .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2022, 47 (89) :37956-37966
[5]   Improvement of formability for fabricating thin continuously corrugated structures in sheet metal forming process [J].
Choi, Sung-Woo ;
Park, Sang Hu ;
Jeong, Ho-Seung ;
Cho, JongRae ;
Park, Seonghun ;
Ha, Man Yeong .
JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY, 2012, 26 (08) :2397-2403
[6]   An investigation into the use of additive manufacture for the production of metallic bipolar plates for polymer electrolyte fuel cell stacks [J].
Dawson, Richard J. ;
Patel, Anant J. ;
Rennie, Allan E. W. ;
White, Simon .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2015, 45 (07) :637-645
[7]   DISCUSSION OF STATIC STRAIN AGING IN COMMERCIAL PURITY ALPHA TITANIUM [J].
DELOBELLE, P ;
OYTANA, C .
METALLURGICAL TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1978, 9 (05) :740-741
[8]   Fabrication of titanium bipolar plates for proton exchange membrane fuel cells by uniform pressure electromagnetic forming [J].
Dong, Pengxin ;
Li, Zhangzhe ;
Feng, Sheng ;
Wu, Zelin ;
Cao, Quanliang ;
Li, Liang ;
Chen, Qi ;
Han, Xiaotao .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (78) :38768-38781
[9]   STATIC STRAIN-AGING IN COMMERCIAL PURITY ALPHA-TITANIUM [J].
DONOSO, JR ;
REEDHILL, RE .
METALLURGICAL TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1977, 8 (06) :945-948
[10]   Recent development of hydrogen and fuel cell technologies: A review [J].
Fan, Lixin ;
Tu, Zhengkai ;
Chan, Siew Hwa .
ENERGY REPORTS, 2021, 7 :8421-8446