Synthesis of N-[2-(3,5-Diallyl-2,4,6-trioxo-1,3,5-triazinan-1-yl)-ethyl]ureas and -Carbamates

被引：0

作者：

Kolyamshin, O. A. ^{[1
]}

Mitrasov, Yu. N. ^{[2
]}

Danilov, V. A. ^{[1
]}

Kuz'min, M. V. ^{[1
]}

Ivanova, K. Yu. ^{[1
]}

机构：

[1] IN Ulyanov Chuvash State Univ, Cheboksary 428015, Russia

[2] Yakovlev Chuvash State Pedag Univ, Cheboksary 428000, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 59卷 / 04期

关键词：

diallyl isocyanurates; ureas; carbamates; mass spectrometry; IR and H-1 NMR spectroscopy;

D O I：

10.1134/S1070428023040073

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1-(2-Aminoethyl)-3,5-diallyl-1,3,5-triazinane-2,4,6-trione reacted with phenyl isocyanate and hexa-methylene diisocyanate to give previously unknown isocyanurates and bis-isocyanurates containing one or two urea fragments, respectively. The reaction of 3,5-diallyl-1-(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione with phenyl isocyanate afforded 2-(3,5-diallyl-2,4,6-trioxo-1,3,5-triazinan-1-yl)ethyl phenylcarbamate, and the alkylation of 3,5-diallyl-1,3,5-triazinane-2,4,6-trione sodium salt with bis(2-chloroethyl) hexane-1,6-diyldi-carbamate produced bis[2-(3,5-diallyl-2,4,6-trioxo-1,3,5-triazinan-1-yl)ethyl] hexane-1,6-diyldicarbamate. Physical and spectroscopic properties of the synthesized isocyanurates and bis-isocyanurates were studied.

引用

页码：606 / 610

页数：5

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