Synthesis of N-[2-(3,5-Diallyl-2,4,6-trioxo-1,3,5-triazinan-1-yl)-ethyl]ureas and -Carbamates

被引：0
|
作者：
Kolyamshin, O. A. [1 ]
Mitrasov, Yu. N. [2 ]
Danilov, V. A. [1 ]
Kuz'min, M. V. [1 ]
Ivanova, K. Yu. [1 ]
机构：
[1] IN Ulyanov Chuvash State Univ, Cheboksary 428015, Russia
[2] Yakovlev Chuvash State Pedag Univ, Cheboksary 428000, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 59卷 / 04期
关键词：
diallyl isocyanurates; ureas; carbamates; mass spectrometry; IR and H-1 NMR spectroscopy;
D O I：
10.1134/S1070428023040073
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
1-(2-Aminoethyl)-3,5-diallyl-1,3,5-triazinane-2,4,6-trione reacted with phenyl isocyanate and hexa-methylene diisocyanate to give previously unknown isocyanurates and bis-isocyanurates containing one or two urea fragments, respectively. The reaction of 3,5-diallyl-1-(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione with phenyl isocyanate afforded 2-(3,5-diallyl-2,4,6-trioxo-1,3,5-triazinan-1-yl)ethyl phenylcarbamate, and the alkylation of 3,5-diallyl-1,3,5-triazinane-2,4,6-trione sodium salt with bis(2-chloroethyl) hexane-1,6-diyldi-carbamate produced bis[2-(3,5-diallyl-2,4,6-trioxo-1,3,5-triazinan-1-yl)ethyl] hexane-1,6-diyldicarbamate. Physical and spectroscopic properties of the synthesized isocyanurates and bis-isocyanurates were studied.
引用
收藏
页码：606 / 610
页数：5
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