Lignin-Derived Carbon Nanofibers Loaded with TiO2 Enables Efficient Photocatalysis

被引:7
作者
Zhai, Gongxun [1 ]
Zhou, Jialiang [1 ,2 ]
Xie, Min [1 ]
Jia, Chao [1 ]
Hu, Zexu [1 ]
Xiang, Hengxue [1 ]
Zhu, Meifang [1 ]
机构
[1] Donghua Univ, Coll Mat Sci & Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China
[2] Jiangsu Gem Adv Fiber Mat Res Inst Co Ltd, Nantong 226000, Peoples R China
基金
中国国家自然科学基金;
关键词
carbon nanofibers; electrospinning; lignin; photocatalysis; water treatment; COMPOSITES; FIBERS; ANATASE;
D O I
10.1002/adsu.202200459
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The high value-added application of lignin is of great significance for the effective utilization of biomass and environmental protection. In this work, TiO2-loaded lignin-derived carbon nanofibers (TiO2@LCNFs) are developed by the process of electrospinning, per-oxidation, and carbonization. The effects of TiO2 content, carbonization temperature, initial RhB concentration, and solution pH value on the photocatalytic efficiency are systematically studied. Up to 86% photocatalytic efficiency and excellent cycling stability of the TiO2@LCNFs to rhodamine B under optimized conditions are achieved. The superior catalytic property of the TiO2@LCNFs can be attributed to the synergistic effect of the uniform distribution of TiO2 on the fiber surface and the good electrical conductivity of LCNFs. It is expected that this work will provide some guidance for the preparation of efficient photocatalytic materials, especially those based on biomass-derived fiber materials.
引用
收藏
页数:8
相关论文
共 38 条
[1]   Photocatalytic degradation of dyes by AgBr/Ag3PO4 and the ecotoxicities of their degraded products [J].
Amornpitoksuk, Pongsaton ;
Suwanboon, Sumetha .
CHINESE JOURNAL OF CATALYSIS, 2016, 37 (05) :711-719
[2]   Carbon fibres from renewable resources: the role of the lignin molecular structure in its blendability with biobased poly(ethylene terephthalate) [J].
Beaucamp, Anne ;
Wang, Yan ;
Culebras, Mario ;
Collins, Maurice N. .
GREEN CHEMISTRY, 2019, 21 (18) :5063-5072
[3]   Carbon fibers derived from commodity polymers: A review [J].
Brown, Kenneth R. ;
Harrell, Timothy M. ;
Skrzypczak, Luke ;
Scherschel, Alexander ;
Wu, H. Felix ;
Li, Xiaodong .
CARBON, 2022, 196 :422-439
[4]   N doped-TiO2 coupled to BiVO4 with high performance in photodegradation of Ofloxacin antibiotic and Rhodamine B dye under visible light [J].
Cipagauta-Diaz, S. ;
Estrella-Gonzalez, A. ;
Navarrete-Magana, M. ;
Gomez, R. .
CATALYSIS TODAY, 2022, 394 :445-457
[5]   Valorization of lignin in polymer and composite systems for advanced engineering applications - A review [J].
Collins, Maurice N. ;
Nechifor, Marioara ;
Tanasa, Fulga ;
Zanoaga, Madalina ;
McLoughlin, Anne ;
Strozyk, Michal A. ;
Culebras, Mario ;
Teaca, Carmen-Alice .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2019, 131 :828-849
[6]   Synthesis of TiO2@lignin based carbon nanofibers composite materials with highly efficient photocatalytic to methylene blue dye [J].
Dai, Zhong ;
Ren, Penggang ;
Cao, Qiping ;
Gao, Xin ;
He, Wenwei ;
Xiao, Yizhou ;
Jin, Yanling ;
Ren, Fang .
JOURNAL OF POLYMER RESEARCH, 2020, 27 (05)
[7]   AC conductivity studies of PMMA/TiO2 composites [J].
Devikala, S. ;
Kamaraj, P. ;
Arthanareeswari, M. .
MATERIALS TODAY-PROCEEDINGS, 2018, 5 (02) :8678-8682
[8]   Effect of aramid and carbon fibers with nano carbon particles on the mechanical properties of EPDM rubber thermal insulators for solid rocket motors application [J].
Enew, Ahmed M. ;
Abd Elfattah, M. ;
Fouda, Safaa R. ;
Hawash, Samah A. .
POLYMER TESTING, 2021, 103
[9]   Manufacture and application of lignin-based carbon fibers (LCFs) and lignin-based carbon nanofibers (LCNFs) [J].
Fang, Wei ;
Yang, Sheng ;
Wang, Xi-Luan ;
Yuan, Tong-Qi ;
Sun, Run-Cang .
GREEN CHEMISTRY, 2017, 19 (08) :1794-1827
[10]   Lignin as Renewable Raw Material [J].
Garcia Calvo-Flores, Francisco ;
Dobado, Jose A. .
CHEMSUSCHEM, 2010, 3 (11) :1227-1235