Hollow ZnO/ZnFe2O4 microspheres anchored graphene aerogels as a high-efficiency microwave absorber with thermal insulation and hydrophobic performances

被引:67
作者
Wang, Wei [1 ]
Wang, Yan [1 ]
Lu, Zhao [1 ]
Cheng, Runrun [1 ]
Zheng, Hao [1 ]
机构
[1] Xian Technol Univ, Sch Mat & Chem Engn, Xian 710021, Peoples R China
基金
中国国家自然科学基金;
关键词
Microwave absorption; Magnetic properties; Radar cross section; Hydrophobicity; Heat insulation; ELECTROMAGNETIC-WAVE ABSORBER; HETEROSTRUCTURE DESIGN; REDUCED GRAPHENE; ABSORPTION; LIGHTWEIGHT; COMPOSITE; NANOCOMPOSITES; CONSTRUCTION; MICROSTRUCTURE;
D O I
10.1016/j.carbon.2022.11.103
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The design of aerogels with high-performance electromagnetic wave absorption, thermal insulation and hy-drophobic properties is of great significance for application in complex and extreme environments. In order to meet the above requirements, we synthesized an aerogel-based microwave absorber with multiple components. Graphene sheets were interconnected to form a 3D framework, and the ZnO/ZnFe2O4 hollow microspheres were uniformly distributed throughout the graphene aerogel. Significantly, the microwave absorption properties of the aerogel resulted in an ultrabroad bandwidth (9.1 GHz) and strong absorption (reflection loss of-65.2 dB). In particular, its specific reflection loss values were significantly higher than those of current magnetic-dielectric absorbing materials with similar components. In addition, the aerogel exhibited strong hydrophobicity and excellent thermal insulation properties, owing to its porous structure. This study provides new insights into the design of next-generation microwave absorbing materials with multifunctional application.
引用
收藏
页码:397 / 409
页数:13
相关论文
共 68 条
[1]   A resilient and lightweight bacterial cellulose-derived C/rGO aerogel-based electromagnetic wave absorber integrated with multiple functions [J].
Bai, Tiantian ;
Guo, Yan ;
Wang, Dedong ;
Liu, Hu ;
Song, Gang ;
Wang, Yaming ;
Guo, Zhanhu ;
Liu, Chuntai ;
Shen, Changyu .
JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (09) :5566-5577
[2]   Genetic Dielectric Genes Inside 2D Carbon-Based Materials with Tunable Electromagnetic Function at Elevated Temperature [J].
Cao, Mao-Sheng ;
Shu, Jin-Cheng ;
Wen, Bo ;
Wang, Xi-Xi ;
Cao, Wen-Qiang .
SMALL STRUCTURES, 2021, 2 (11)
[3]   Construction of C-Si heterojunction interface in SiC whisker/reduced graphene oxide aerogels for improving microwave absorption [J].
Chen, Jing-Peng ;
Jia, Hui ;
Liu, Zhuo ;
Kong, Qing-Qiang ;
Hou, Zhi-Hui ;
Xie, Li-Jing ;
Sun, Guo-Hua ;
Zhang, Shou-Chun ;
Chen, Cheng-Meng .
CARBON, 2020, 164 :59-68
[4]   Banana Leaflike C-Doped MoS2 Aerogels toward Excellent Microwave Absorption Performance [J].
Cheng, Jin-Bo ;
Zhao, Hai-Bo ;
Cao, Min ;
Li, Meng-En ;
Zhang, Ai-Ning ;
Li, Shu-Liang ;
Wang, Yu-Zhong .
ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (23) :26301-26312
[5]   Heterostructure design of MOFs derived Co9S8/FeCoS2/C composite with efficient microwave absorption and waterproof functions [J].
Cheng, Runrun ;
Wang, Yan ;
Di, Xiaochuang ;
Lu, Zhao ;
Wang, Ping ;
Wu, Xinming .
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2022, 129 :15-26
[6]   Construction of MOF-derived plum-like NiCo@C composite with enhanced multi-polarization for high-efficiency microwave absorption [J].
Cheng, Runrun ;
Wang, Yan ;
Di, Xiaochuang ;
Lu, Zhao ;
Wang, Ping ;
Ma, Mingliang ;
Ye, Jinrui .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2022, 609 :224-234
[7]   Heterostructure design of Ni/C/porous carbon nanosheet composite for enhancing the electromagnetic wave absorption [J].
Di, Xiaochuang ;
Wang, Yan ;
Lu, Zhao ;
Cheng, Runrun ;
Yang, Longqi ;
Wu, Xinming .
CARBON, 2021, 179 :566-578
[8]   Wheat flour-derived nanoporous carbon@ZnFe2O4 hierarchical composite as an outstanding microwave absorber [J].
Di, Xiaochuang ;
Wang, Yan ;
Fu, Yuqiao ;
Wu, Xinming ;
Wang, Ping .
CARBON, 2021, 173 (173) :174-184
[9]   Electrostatic Adsorption Enables Layer Stacking Thickness-Dependent Hollow Ti3C2Tx MXene Bowls for Superior Electromagnetic Wave Absorption [J].
Du, Qinrui ;
Men, Qiaoqiao ;
Li, Ruosong ;
Cheng, Youwei ;
Zhao, Biao ;
Che, Renchao .
SMALL, 2022, 18 (47)
[10]   Synergistically enhanced heat conductivity-microwave absorption capabilities of g-C3N4@Fe@C hollow micro-polyhedra via interface and composition modulation [J].
Fan, Baoxin ;
Xing, Lu ;
Yang, Kaixia ;
Zhou, Fanjie ;
He, Qianmei ;
Tong, Guoxiu ;
Wu, Wenhua .
CHEMICAL ENGINEERING JOURNAL, 2023, 451