A cyclodextrin-based turn-off fluorescent probe for naked-eye detection of copper ions in aqueous solution

被引:21
作者
Wang, Jin [1 ]
Yang, Xiao-Qin [1 ]
Li, Na [1 ]
Wang, Li-Li
Xu, Xin-Ying [1 ]
Zhang, Ce [2 ]
机构
[1] Yancheng Teachers Univ, Jiangsu Prov Engn Res Ctr Tumor Targeted Nano Diag, Sch Pharm, Yancheng 224007, Jiangsu, Peoples R China
[2] Nanjing Drum Tower Hosp Grp, Suqian Hosp, Suqian 223800, Jiangsu, Peoples R China
关键词
-Cyclodextrin; Thiosemicarbazide; Fluorescent probe; Copper ions detection; BETA-CYCLODEXTRIN; CU2+ IONS; SENSOR; CHEMOSENSOR; RECOGNITION;
D O I
10.1016/j.saa.2022.122069
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
A novel fluorescent probe L consisting of beta-Cyclodextrin (beta-CD) and thiosemicarbazide moieties was designed for copper ions detection. Apparent fluorescence quenching of probe L in Tris-HCl(pH = 7.4)solution was observed only in the presence of Cu2+, among other interfering ions. The present probe L was 1:1 complexed with Cu2+ and the detection limit of probe L was calculated to be 1.37 mu M. The results demonstrate that the probe L may provide a convenient method for visual detection of Cu2+ in the environmental and biological systems.
引用
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页数:5
相关论文
共 19 条
[1]   A highly sensitive and selective fluorescent sensor for the determination of copper(II) based on a schiff base [J].
Aksuner, Nur ;
Henden, Emuer ;
Yilmaz, Ibrahim ;
Cukurovali, Alaaddin .
DYES AND PIGMENTS, 2009, 83 (02) :211-217
[2]   Imaging of copper, zinc, and other elements in thin section of human brain samples (Hippocampus) by laser ablation inductively coupled plasma mass spectrometry [J].
Becker, JS ;
Zoriy, MV ;
Pickhardt, C ;
Palomero-Gallagher, N ;
Zilles, K .
ANALYTICAL CHEMISTRY, 2005, 77 (10) :3208-3216
[3]  
Bonomo RP, 1997, CHIRALITY, V9, P341, DOI 10.1002/(SICI)1520-636X(1997)9:4<341::AID-CHIR5>3.0.CO
[4]  
2-G
[5]   Peat as a natural solid-phase for copper preconcentration and determination in a multicommuted flow system coupled to flame atomic absorption spectrometry [J].
Gonzales, A. P. S. ;
Firmino, M. A. ;
Nomura, C. S. ;
Rocha, F. R. P. ;
Oliveira, P. V. ;
Gaubeur, I. .
ANALYTICA CHIMICA ACTA, 2009, 636 (02) :198-204
[6]   Nanopore sensor for copper ion detection using a polyamine decorated β- cyclodextrin as the recognition element [J].
Guo, Yanli ;
Jian, Feifei ;
Kang, Xiaofeng .
RSC ADVANCES, 2017, 7 (25) :15315-15320
[7]   A new rhodamine-based colorimetric chemosensor for naked-eye detection of Cue2+ in aqueous solution [J].
Hu, Yang ;
Zhang, Jing ;
Lv, Yuan-Zheng ;
Huang, Xiao-Huan ;
Hu, Sheng-li .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2016, 157 :164-169
[8]  
Jing H.U., 1999, CHINESE CHEM LETT, P273
[9]   β-Cyclodextrin included coumarin derivatives as selective fluorescent sensors for Cu2+ ions in HeLa cells [J].
Khan, Raihana Imran ;
Pitchumani, Kasi .
RSC ADVANCES, 2016, 6 (24) :20269-20275
[10]   Selective removal of copper and lead ions by diethylenetriamine-functionalized adsorbent: Behaviors and mechanisms [J].
Liu, Changkun ;
Bai, Renbi ;
Ly, Quan San .
WATER RESEARCH, 2008, 42 (6-7) :1511-1522