Degradation of a poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) compound in different environments

被引:12
作者
Lyshtva, Pavlo [1 ]
Voronova, Viktoria [1 ]
Barbir, Jelena [2 ]
Leal Filho, Walter [2 ]
Kroeger, Silja Denise
Witt, Gesine [2 ]
Miksch, Lukas [3 ]
Sabowski, Reinhard [3 ]
Gutow, Lars [3 ]
Frank, Carina [4 ]
Emmerstorfer-Augustin, Anita [4 ]
Agustin-Salazar, Sarai [5 ]
Cerruti, Pierfrancesco [5 ]
Santagata, Gabriella [5 ]
Stagnaro, Paola [6 ]
D'Arrigo, Cristina [6 ]
Vignolo, Maurizio [6 ]
Krang, Anna -Sara [7 ]
Stroemberg, Emma [7 ]
Lehtinen, Liisa [8 ]
Annunen, Ville [8 ]
机构
[1] Tallinn Univ Technol, Ehitajate Tee 5, EE-19086 Tallinn, Estonia
[2] Hamburg Univ Appl Sci, Ulmenliet 20, D-21033 Hamburg, Germany
[3] Alfred Wegener Inst, Handelshafen 12, D-27570 Bremerhaven, Germany
[4] Austrian Ctr Ind Biotechnol, Krenngasse 37-2, A-8010 Graz, Austria
[5] Natl Council Res, Inst Polymers Composites & Biomat, Via Campi Flegrei 34, Pozzuoli 80078, NA, Italy
[6] CNR, Inst Chem Sci & Technol Giulio Natta, Via De Marini 6, I-16149 Genoa, Italy
[7] IVL Swedish Environm Res Inst, Valhallavagen 81, S-11428 Stockholm, Sweden
[8] Turku Univ Appl Sci, Joukahaisenkatu 3, Turku 20520, Finland
关键词
PHBV; Polymer blends; Degradation; Natural environment; Laboratory scale testing; Morphological properties; BIODEGRADATION; CRYSTALLIZATION; BIOPLASTICS; POLYESTERS; PLA;
D O I
10.1016/j.heliyon.2024.e24770
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) is a promising biodegradable bio-based material, which is designed for a vast range of applications, depending on its composite. This study aims to assess the degradability of a PHBV-based compound under different conditions. The research group followed different methodological approaches and assessed visual and mass changes, mechanical and morphological properties, spectroscopic and structural characterisation, along with thermal behaviour. The Ph-Stat (enzymatic degradation) test and total dry solids (TDS)/total volatile solids (TVS) measurements were carried out. Finally, the team experimentally evaluated the amount of methane and carbon dioxide produced, i.e., the degree of biodegradation under aerobic conditions. According to the results, different types of tests have shown differing effects of environmental conditions on material degradation. In conclusion, this paper provides a summary of the investigations regarding the degradation behaviour of the PHBV-based compound under varying environmental factors. The main strengths of the study lie in its multi-faceted approach, combining assessments of PHBV-based compound degradability under different conditions using various analytical tools, such as visual and mass changes, mechanical and morphological properties, spectroscopic and structural characterization, and thermal behavior. These methods collectively contribute to the robustness and reliability of the undertaken work.
引用
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页数:20
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