Reaction of N-Sulfinyltrifluoromethanesulfonamide with Succinyl Chloride

被引：1
|
作者：
Tolstikova, L. L. [1 ]
Sterkhova, I. V. [1 ]
Shainyan, B. A. [1 ]
机构：
[1] Russian Acad Sci, Favorsky Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 59卷 / 03期
基金：
俄罗斯科学基金会;
关键词：
N-sulfinyltrifluoromethanesulfonamide; 1-(trifluoromethanesulfonyl)pyrrolidine-2; 5-dione; selec-tive C-N bond cleavage; X-ray analysis;
D O I：
10.1134/S1070428023030247
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
N-Sulfinyltrifluoromethanesulfonamide reacted with succinyl chloride to give 1-(trifluoromethane-sulfonyl)pyrrolidine-2,5-dione in high yield. The product structure was proved by X-ray analysis. The reaction of 1-(trifluoromethanesulfonyl)pyrrolidine-2,5-dione with ethanol under mild conditions involved selective opening of the pyrrole ring at the C-N bond with the formation of (1E)-4-ethoxy-4-oxo-N-(trifluoromethane-sulfonyl)butanimidic acid.
引用
收藏
页码：545 / 547
页数：3
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