Core-shell Si3N4@WS2 porous ceramics with improved electromagnetic wave absorption performance

被引:5
|
作者
Bai, Jialin [1 ,2 ]
Huang, Shijie [1 ,2 ]
Yao, Xiumin [1 ]
Liu, Xuejian [1 ]
Huang, Zhengren [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine M, Shanghai 200050, Peoples R China
[2] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1039/d3tc04672a
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ceramic-based absorbing materials have attracted extensive attention in electromagnetic wave (EMW) absorption because they are lightweight and exhibit strong dielectric loss. However, there is still a need for developing the microstructure design of ceramics, and this hinders the further improvement of absorption properties. In this study, core-shell Si3N4@WS2 porous ceramics, with the wave-transmitting phase Si3N4 as the core and the wave-loss phase WS2 as the shell, were prepared using a simple impregnation-hydrothermal method. The core-shell structure provided as large a contact area as possible between WS2 and Si3N4, promoting the formation of heterogeneous interfaces. The as-prepared core-shell Si3N4@WS2 porous ceramics exhibited excellent EMW absorption properties. When thickness was 3.92-4.22 mm, an effective absorption bandwidth of 4.20 GHz was achieved, covering the entire X-band (8.2-12.4 GHz). At a thickness of 4.35 mm, the minimum reflection loss was -65.03 dB. The outstanding EMW absorption performance was attributed to the special core-shell microstructure inducing interfacial polarization loss and optimizing the impedance matching of the material. The findings of this study provide novel insights and feasible strategies for designing ceramic-based absorbing materials with core-shell structures.
引用
收藏
页码:5776 / 5783
页数:8
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