High Performance Self-Driven Photodetectors Based on MoS2 Schottky Barrier Diode

被引:16
作者
Dai, Mengde [1 ]
Wu, Qianqian [1 ]
Wang, Chenglin [1 ]
Liu, Xingyu [1 ]
Zhang, Xiumei [1 ]
Cai, Zhengyang [1 ]
Lin, Liangliang [2 ]
Gu, Xiaofeng [1 ]
Ostrikov, Kostya [3 ,4 ]
Nan, Haiyan [1 ]
Xiao, Shaoqing [1 ]
机构
[1] Jiangnan Univ, Engn Res Ctr IoT Technol Applicat, Dept Elect Engn, Minist Educ,Sch Sci, Wuxi 214122, Peoples R China
[2] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Peoples R China
[3] Queensland Univ Technol QUT, Sch Phys & Chem, Brisbane, Qld 4000, Australia
[4] Queensland Univ Technol QUT, QUT Ctr Mat Sci, Brisbane, Qld 4000, Australia
关键词
MoS2; Schottky diodes; self-driven photodetectors; soft plasma; MONOLAYER MOS2; WORK FUNCTION; GRAPHENE; CONTACTS;
D O I
10.1002/adom.202301900
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Practical application of two-dimensional transition metal dichalcogenides (2D TMDCs) involves creating a p-n diode and a Schottky diode. Unlike p-n diodes, the research of 2D material-based Schottky diodes especially in the application field of photodetectors is lacking. Here, a Schottky diode is fabricated by depositing Pt and Ni on the MoS2 to form Schottky and ohmic contacts, respectively. The MoS2 Schottky diode exhibits a rectification ratio of 2.36 x 10(3) and an ideality factor of 1.12. The electrical characteristics of Ni-MoS2-Ni and Pt-MoS2-Pt field effect transistors are systematically compared. The Schottky barrier height is estimated to be 94.2 meV by using the thermionic emission theory. The Schottky diode device can exhibit excellent self-powered photodetection performance in the visible to near-infrared region (447-940 nm) due to the strong built-in electric field originating from the Schottky barrier at the MoS2/Pt interface. The maximum detectivity reaches 2.09 x 10(12) Jones with a response time of 52.6 ms under 940 nm laser illumination. Furthermore, the photodetection performance of such a Schottky diode can be further improved by NH3 plasma doping treatment. This work provides not only a simple approach to construct a 2D materials-based Schottky diode photodetector but also a post treatment technique to further improve the device performance.
引用
收藏
页数:10
相关论文
共 47 条
[1]   Improved Contacts and Device Performance in MoS2 Transistors Using a 2D Semiconductor Interlayer [J].
Andrews, Kraig ;
Bowman, Arthur ;
Rijal, Upendra ;
Chen, Pai-Yen ;
Zhou, Zhixian .
ACS NANO, 2020, 14 (05) :6232-6241
[2]   Photovoltaic effect in few-layer black phosphorus PN junctions defined by local electrostatic gating [J].
Buscema, Michele ;
Groenendijk, Dirk J. ;
Steele, Gary A. ;
van der Zant, Herre S. J. ;
Castellanos-Gomez, Andres .
NATURE COMMUNICATIONS, 2014, 5
[3]   Schottky barrier detectors on GaN for visible-blind ultraviolet detection [J].
Chen, Q ;
Yang, JW ;
Osinsky, A ;
Gangopadhyay, S ;
Lim, B ;
Anwar, MZ ;
Khan, MA ;
Kuksenkov, D ;
Temkin, H .
APPLIED PHYSICS LETTERS, 1997, 70 (17) :2277-2279
[4]  
Chen X., 2016, Angew. Chem, V128, P5897, DOI [DOI 10.1002/ANGE.201510219, 10.1002/ange.201510219]
[5]   Lateral MoS2 p-n Junction Formed by Chemical Doping for Use in High-Performance Optoelectronics [J].
Choi, Min Sup ;
Qu, Deshun ;
Lee, Daeyeong ;
Liu, Xiaochi ;
Watanabe, Kenji ;
Taniguchi, Takashi ;
Yoo, Won Jong .
ACS NANO, 2014, 8 (09) :9332-9340
[6]   Black Phosphorus-Monolayer MoS2 van der Waals Heterojunction p-n Diode [J].
Deng, Yexin ;
Luo, Zhe ;
Conrad, Nathan J. ;
Liu, Han ;
Gong, Yongji ;
Najmaei, Sina ;
Ajayan, Pulickel M. ;
Lou, Jun ;
Xu, Xianfan ;
Ye, Peide D. .
ACS NANO, 2014, 8 (08) :8292-8299
[7]   A strain tunable single-layer MoS2 photodetector [J].
Gant, Patricia ;
Huang, Peng ;
de Lara, David Perez ;
Guo, Dan ;
Frisenda, Riccardo ;
Castellanos-Gomez, Andres .
MATERIALS TODAY, 2019, 27 :8-13
[8]   Visible to near-infrared photodetectors based on MoS2 vertical Schottky junctions [J].
Gong, Fan ;
Fang, Hehai ;
Wang, Peng ;
Su, Meng ;
Li, Qing ;
Ho, Johnny C. ;
Chen, Xiaoshuang ;
Lu, Wei ;
Liao, Lei ;
Wang, Jun ;
Hu, Weida .
NANOTECHNOLOGY, 2017, 28 (48)
[9]   Atomically Thin Ohmic Edge Contacts Between Two-Dimensional Materials [J].
Guimaraes, Marcos H. D. ;
Gao, Hui ;
Han, Yimo ;
Kang, Kibum ;
Xie, Saien ;
Kim, Cheol-Joo ;
Muller, David A. ;
Ralph, Daniel C. ;
Park, Jiwoong .
ACS NANO, 2016, 10 (06) :6392-6399
[10]   A High-Performance Schottky Photodiode with Asymmetric Metal Contacts Constructed on 2D Bi2O2Se [J].
Han, Jianfu ;
Fang, Chaocheng ;
Yu, Ming ;
Cao, Juexian ;
Huang, Kai .
ADVANCED ELECTRONIC MATERIALS, 2022, 8 (07)