Thermally-exfoliated graphene Oxide/ZnO nanocomposite catalysts for photocatalytic hydrogen evolution and antibacterial activities

被引:18
作者
Genc, Muenevver Tuna [1 ]
Sarilmaz, Adem [3 ]
Dogan, Semih [5 ,6 ]
Cekceog, Ilknur Aksoy [1 ]
Ozen, Abdurrahman [4 ]
Aslan, Emre [2 ]
Okan, Burcu Saner [5 ,6 ,7 ]
Jaafar, Juhana [8 ]
Ozel, Faruk [3 ]
Ersoz, Mustafa [8 ,9 ]
Patir, Imren Hatay [1 ]
机构
[1] Selcuk Univ, Dept Biotechnol, TR-42030 Konya, Turkiye
[2] Selcuk Univ, Dept Biochem, Konya 42030, Turkiye
[3] Karamanoglu Mehmetbey Univ, Dept Met & Mat Engn, Karaman 70200, Turkiye
[4] Suleyman Demirel Univ, Dept Mech Engn, TR-32260 Isparta, Turkiye
[5] Sabanci Univ, Integrated Mfg Technol Res & Applicat Ctr, Teknopk Istanbul, TR-34906 Istanbul, Turkiye
[6] Sabanci Univ, Composite Technol Ctr Excellence, Teknopk Istanbul, TR-34906 Istanbul, Turkiye
[7] Sabanci Univ, Fac Engn & Nat Sci, Mat Sci & Nanoengn, TR-34956 Istanbul, Turkiye
[8] Univ Teknol Malaysia, Fac Chem & Energy Engn, Adv Membrane Technol Res Ctr AMTEC, Utm Johor Bahru 81310, Johor, Malaysia
[9] Selcuk Univ, Dept Chem, TR-42030 Konya, Turkiye
关键词
Antibacterial activity; Carbon nanomaterials; Graphene-derived materials; Hydrogen evolution; Nanocomposite catalyst; COMPOSITE PHOTOCATALYST; H-2; PRODUCTION; NANOPARTICLES; DEGRADATION; PERFORMANCE; COCATALYST; NANOSHEETS; MOSX; HETEROJUNCTIONS; SHEETS;
D O I
10.1016/j.ijhydene.2023.04.185
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Carbon nanomaterials are of great interest due to their enhanced charge separation in hydrogen evolution reactions. Herein, heterostructured TEGO/ZnO nanocomposite catalyst was obtained by combining 3D multilayer graphene-like nanomaterial obtained by green process from recycled carbon source with ZnO to improve photocatalytic activity. Here, photodeposition of MoSx and Pt in aqueous solution is performed on TEGO/ZnO nano composite to obtain TEGO/ZnO/MoSx and TEGO/ZnO/Pt by reducing (NH4)2MoS4 and H2-PtCl6.6H2O, respectively. Photodeposited MoSx and Pt on TEGO/ZnO nanocomposite resulted in enhanced photocatalytic activity and stability due to increased active sites and enhanced electron transfer ability due to cocatalyst effect. In addition, antibacterial activity of TEGO/ZnO nanocomposite against Escherichia coli and Staphylococcus aureus was investigated by bacterial growth kinetic assay. This work could open up a new nano material for chemical and biological applications.(c) 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:30407 / 30419
页数:13
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