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Synthesis and Properties of Carbazole-fused Thioindigo Oligomers
被引:0
|作者:
Sugimoto, Ryuichi
[1
]
Konishi, Souma
[1
]
Saitoh, Hiroki
[1
]
Kimoto, Atsushi
[1
]
机构:
[1] Konan Univ, Fac Sci & Engn, Dept Chem, 8-9-1 Okamoto, Higashinada, Kobe 6588501, Japan
关键词:
Rigid pi-electron system;
Thioindigo;
Carbazole;
LIQUID-CRYSTALS;
LADDER POLYMERS;
DYES;
D O I:
10.1246/cl.230072
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
A new class of rigid and planar compounds, carbazole-fused thioindigo oligomers (Cz(n)TI(n)11, n = 2, 3), was prepared using palladium-catalyzed carbon -sulfur bond formation and intramolecular Friedel-Crafts acylation as the key reactions. The reaction conditions for the formation of the thioindigo moiety, as well as the basic photo-and electrochemical prop-erties of the oligomers, including photochromic behavior, were investigated.
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页码:354 / 357
页数:4
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