The equations of state of statically compressed palladium and rhodium

被引：7

作者：

Frost, Mungo ^{[1
]}

Smith, Dean ^{[2
,3
]}

McBride, Emma E. E. ^{[1
,4
]}

Smith, Jesse S. S. ^{[3
]}

Glenzer, Siegfried H. H. ^{[1
]}

机构：

[1] SLAC Natl Accelerator Lab, 2575 Sand Hill Rd, Menlo Pk, CA 94025 USA

[2] Univ Nevada, Nevada Extreme Condit Lab, Las Vegas, NV 89154 USA

[3] Argonne Natl Lab, Xray Sci Div, HPCAT, Argonne, IL 60439 USA

[4] Queens Univ Belfast, Sch Math & Phys, Belfast, North Ireland

来源：

JOURNAL OF APPLIED PHYSICS | 2023年 / 134卷 / 03期

关键词：

X-RAY-DIFFRACTION; HIGH-PRESSURE; OF-STATE; SYSTEM; TEMPERATURE; HYDRIDES; ALLOYS; PD;

D O I：

10.1063/5.0161038

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The pressure-volume equations of state of palladium and rhodium statically compressed in neon are presented. Vinet fits give parameters for palladium. V-0 = 58.678(73) angstrom(3), B-0 = 189.3(30) GPa, B-0 ' = 5.473(63), and rhodium. V-0 = 55.062(63) angstrom(3), B-0 = 241.3(65) GPa, B-0 ' = 5.34(24). Both metals are observed to react with hydrocarbons under pressure to form hydrides. Existing equations of state are discussed with regard to potential inadvertent hydrogen contamination as a source for discrepancies and anomalous fitted parameters.

引用

页数：5

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