N,N-Bis(9-methyl-3-carbazolyl)-4-anisidine as an Electroactive Material for Use in Perovskite Solar Cells

被引：0

作者：

Keruckas, Jonas ^{[1
]}

Janasik, Patryk ^{[2
,3
]}

Keruckiene, Rasa ^{[1
,2
]}

Czulkin, Pawel ^{[2
,3
]}

Czichy, Malgorzata ^{[2
,3
]}

Lapkowski, Mieczyslaw ^{[2
,3
,5
]}

Volyniuk, Dmytro ^{[1
]}

Durgaryan, Ranush ^{[1
,4
]}

Kim, Byeong Jo ^{[4
]}

Boschloo, Gerrit ^{[4
]}

Grazulevicius, Juozas Vidas ^{[1
]}

机构：

[1] Kaunas Univ Technol, Dept Polymer Chem & Technol, LT-51423 Kaunas, Lithuania

[2] Silesian Tech Univ, Dept Phys Chem & Technol Polymers, PL-44100 Gliwice, Poland

[3] Silesian Tech Univ, Ctr Organ & Nanohybrid Elect, PL-44100 Gliwice, Poland

[4] Uppsala Univ, Dept Chem, Angstrom Lab, Phys Chem, S-75120 Uppsala, Sweden

[5] Polish Acad Sci Zabrze, Ctr Polymer & Carbon Mat, PL-41819 Zabrze, Poland

来源：

ACS APPLIED ENERGY MATERIALS | 2023年 / 6卷 / 11期

关键词：

perovskite solar cell; time-of-flight; electrooxidationmechanism; EIS; DFT; HOLE-TRANSPORTING MATERIALS; MOLECULAR GLASSES; HOST MATERIALS; CARBAZOLE; TRIPHENYLAMINE; ENHANCEMENT; DERIVATIVES; EFFICIENCY;

D O I：

10.1021/acsaem.3c00102

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Di-(9-methyl-3-carbazolyl)-(4-anisyl)-amine is presentedas an effectivehole-transporting material suitable for application in perovskitesolar cells. It is obtained by a three-step synthesis from inexpensivestarting compounds. It has a relatively high glass transition temperatureof 93 degrees C and thermal stability with 5% weight loss at 374 degrees C.The compound exhibits reversible double-wave electrochemical oxidationbelow +1.5 V and polymerization at higher potential. A mechanism forits oxidation is proposed based on electrochemical impedance and electronspin resonance spectroscopy investigations, ultraviolet-visible-near-infraredabsorption spectroelectrochemistry results, and density functionaltheory-based calculations. Vacuum-deposited films of the compoundare characterized by a low ionization potential of 5.02 +/- 0.06eV and hole mobility of 10(-3) cm(2)/(Vs)at an electric field of 4 x 10(5) V/cm. The newly synthesizedcompound has been used to fabricate dopant-free hole-transportinglayers in perovskite solar cells. A power conversion efficiency of15.5% was achieved in a preliminary study.

引用

页码：5720 / 5728

页数：9

共 38 条

[1] Influence of ionizing dopants on charge transport in organic semiconductors [J].

Abate, Antonio ;

Staff, Daniel R. ;

Hollman, Derek J. ;

Snaith, Henry J. ;

Walker, Alison B. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (03) :1132-1138

[2] Simply designed carbazole-based hole transporting materials for efficient perovskite solar cells [J].

Benhattab, Safia ;

Cho, An-Na ;

Nakar, Rana ;

Berton, Nicolas ;

Tran-Van, Francois ;

Park, Nam-Gyu ;

Schmaltz, Bruno .

ORGANIC ELECTRONICS, 2018, 56 :27-30

[3] Triphenylamine and some of its derivatives as versatile building blocks for organic electronic applications [J].

Blanchard, Philippe ;

Malacrida, Claudia ;

Cabanetos, Clement ;

Roncali, Jean ;

Ludwigs, Sabine .

POLYMER INTERNATIONAL, 2019, 68 (04) :589-606

[4] Optically and electrically excited intermediate electronic states in donor:acceptor based OLEDs [J].

Bunzmann, Nikolai ;

Weissenseel, Sebastian ;

Kudriashova, Liudmila ;

Gruene, Jeannine ;

Krugmann, Benjamin ;

Grazulevicius, Juozas Vidas ;

Sperlich, Andreas ;

Dyakonov, Vladimir .

MATERIALS HORIZONS, 2020, 7 (04) :1126-1137

[5] Engineering of dendritic dopant-free hole transport molecules: enabling ultrahigh fill factor in perovskite solar cells with optimized dendron construction [J].

Chen, Wei ;

Wang, Yang ;

Liu, Bin ;

Gao, Yajun ;

Wu, Ziang ;

Shi, Yongqiang ;

Tang, Yumin ;

Yang, Kun ;

Zhang, Yujie ;

Sun, Weipeng ;

Feng, Xiyuan ;

Laquai, Frederic ;

Woo, Han Young ;

Djurisic, Aleksandra B. ;

Guo, Xugang ;

He, Zhubing .

SCIENCE CHINA-CHEMISTRY, 2021, 64 (01) :41-51

[6] Carbazole-based hole transporting material for solid state dye-sensitized solar cells: Influence of the purification methods [J].

Degbia, M. ;

Ben Manaa, M. ;

Schmaltz, B. ;

Berton, N. ;

Boucle, J. ;

Antony, R. ;

Van, F. Tran .

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2016, 43 :90-95

[7] Enhancement of Hole Extraction Efficiency of Dibenzothiophenes by Substitution Engineering: Toward Additive-Free Perovskite Solar Cells with Power Conversion Efficiency Exceeding 20% [J].

Durgaryan, Ranush ;

Simokaitiene, Jurate ;

Volyniuk, Dmytro ;

Bezvikonnyi, Oleksandr ;

Danyliv, Yan ;

Kim, Byeong Jo ;

Woon, Kai Lin ;

Sini, Gjergji ;

Boschloo, Gerrit ;

Grazulevicius, Juozas Vidas .

SOLAR RRL, 2022, 6 (07)

[8]

GAUTHIER S, 1987, SYNTHESIS-STUTTGART, P383

[9] Excitation Dynamics in Low Band Gap Donor-Acceptor Copolymers and Blends [J].

Gieseking, Bjoern ;

Jaeck, Berthold ;

Preis, Eduard ;

Jung, Stefan ;

Forster, Michael ;

Scherf, Ullrich ;

Deibel, Carsten ;

Dyakonov, Vladimir .

ADVANCED ENERGY MATERIALS, 2012, 2 (12) :1477-1482

[10] THE ELECTRICAL DOUBLE LAYER AND THE THEORY OF ELECTROCAPILLARITY [J].

GRAHAME, DC .

CHEMICAL REVIEWS, 1947, 41 (03) :441-501

← 1 2 3 4 →