Co(II)-doped hybrid Zn(II) tetraborate complexes, [ZnxCo(1-x)(1,3-dap)B4O7] (1,3-dap=1,3-diaminopropane): BET analysis and N2/H2O/D2O adsorption studies

被引：0

作者：

Liu, Lei ^{[1
]}

Pan, Chun-Yang ^{[1
]}

He, Yong ^{[1
]}

Zhong, Li-Juan ^{[1
]}

Beckett, Michael A. ^{[2
]}

机构：

[1] Guangdong Univ Technol, Sch Light Ind & Chem Engn, Guangzhou 510006, Peoples R China

[2] Bangor Univ, Sch Nat Sci, Bangor LL57 2UW, Gwynedd, Wales

来源：

DALTON TRANSACTIONS | 2024年 / 53卷 / 10期

基金：

中国国家自然科学基金;

关键词：

ORGANIC FRAMEWORKS; SURFACE-AREA; BORATE; ZEOLITES; WATER; MECHANISM; CATIONS; SERIES; SALTS;

D O I：

10.1039/d4dt00117f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of mono/bimetallic isostructural hybrid tetraborates of the general formula [ZnxCo(1-x)(1,3-dap)B4O7] has been prepared using a solvothermal method. Their adsorption/desorption curves for H2O and D2O demonstrate that these materials have a stronger affinity for H2O than for D2O and enrich the D2O content of D2O/H2O mixtures.

引用

页码：4637 / 4642

页数：6

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