Diazinon and MCPA photo-reduction with sulfite excitation under UV irradiation and reducing agents' generation

Diazinon (DIZ) and 4-Chloro-2-methylphenoxyacetic acid (MCPA) herbicide and widely used in agricultural lands. Present study investigates diazinon and 4-chloro-2-methylphenoxyacetic acid photo-reduction via UV/Sulfite (US) in as Advanced Reduction Processes (ARP). The ideal pH was Molar ratio of sulfite: DIZ or MCPA 1:1 and, 20 min reaction time, and pH 9, in which about 100 % reduction of DIZ and MCPA with a concentration of 10 mg L-1 was achieved and the optimal conditions were considered. Kinetic investigation increasing DIZ and MCPA concentration from 5 to 20 mgL-1, kobs increase about from 0.151 to 0.234 for DIZ and from 0.231 to 0.589 min- 1. Also, reaction rate (robs) increases about from 0.755 to 4.68 for DIZ and from 1.155 to 11.78 mg L-1.min. The amount of energy consumption in DIZ solution increased from 5 to 20, respectively, from 0.73 to 2.37, and in the reduction of MCPA from 0.47 to 1.49 kWh per cubic meter. According to experiments performed in 30 min with the US process, COD levels were reduced by about 46 % of both pollutants. It is important to note that the BOD/COD ratio rose from about 0.20 to 0.48 after 30 min. Since the index of biodegradability has grown high, it can be concluded that non-biodegradable COD (NBDCOD) convert to biodegradable COD (BDCOD) and toxicity is lower than of before of treatment. This study has been very suggesting that the UV/sulfite method produces effluent with a non-toxic and ecologically beneficial manner by biological treatment or discharge directly in environment.