Light-modulation of gel stiffness: a glyconucleoside based bolaamphiphile as a photo-cleavable low molecular weight gelator

被引：4
作者：
Bansode, Nitin [1 ]
Verget, Julien [1 ]
Barthelemy, Philippe [1 ]
机构：
[1] Univ Bordeaux, UMR CNRS 5320, INSERM U1212, F-33076 Bordeaux, France
来源：
SOFT MATTER | 2023年 / 19卷 / 36期
关键词：
SUPRAMOLECULAR HYDROGELS; RELEASE;
D O I：
10.1039/d3sm00766a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Photo-cleavable glyconucleoside bolaamphiphiles containing a nitrophenyl unit feature gelation abilities in aqueous media. The stiffness of the resulting gels can be modulated upon light irradiation thanks to the photocleavage reaction of nitrophenyl moieties. A photo-cleavable glyconucleoside bolaamphiphile (GNBAhv) featuring a nitrophenyl unit is reported. The stiffness of the GNBAhv based gels can be modulated upon light irradiation.
引用
收藏
页码：6867 / 6870
页数：4
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  • [1] Synthetic alternatives to Matrigel
    Aisenbrey, Elizabeth A.
    Murphy, William L.
    [J]. NATURE REVIEWS MATERIALS, 2020, 5 (07) : 539 - 551
  • [2] Reversible Hydrogel Photopatterning: Spatial and Temporal Control over Gel Mechanical Properties Using Visible Light Photoredox Catalysis
    Amir, Faheem
    Liles, Kevin P.
    Delawder, Abigail O.
    Colley, Nathan D.
    Palmquist, Mark S.
    Linder, Houston R.
    Sell, Scott A.
    Barnes, Jonathan C.
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2019, 11 (27) : 24627 - 24638
  • [3] β-Galactosidase instructed self-assembly of supramolecular bolaamphiphiles hydrogelators
    Baillet, Julie
    Gaubert, Alexandra
    Verget, Julien
    Latxague, Laurent
    Barthelemy, Philippe
    [J]. SOFT MATTER, 2020, 16 (33) : 7648 - 7651
  • [4] Supramolecular gels derived from nucleoside based bolaamphiphiles as a light-sensitive soft material
    Baillet, Julie
    Gaubert, Alexandra
    Bassani, Dario M.
    Verget, Julien
    Latxague, Laurent
    Barthelemy, Philippe
    [J]. CHEMICAL COMMUNICATIONS, 2020, 56 (23) : 3397 - 3400
  • [5] A disulfide based low molecular weight gel for the selective sustained release of biomolecules
    Bansode, Nitin D.
    Sindhu, Kotagudda Ranganath
    Morel, Chloe
    Remy, Murielle
    Verget, Julien
    Boiziau, Claudine
    Barthelemy, Philippe
    [J]. BIOMATERIALS SCIENCE, 2020, 8 (11) : 3186 - 3192
  • [6] Controlled release and characterisation of photocaged molecules using in situ LED illumination in solution NMR spectroscopy
    Bramham, Jack E.
    Zalar, Matja
    Golovanov, Alexander P.
    [J]. CHEMICAL COMMUNICATIONS, 2022, 58 (85) : 11973 - 11976
  • [7] Shaping and structuring supramolecular gels
    Chivers, Phillip R. A.
    Smith, David K.
    [J]. NATURE REVIEWS MATERIALS, 2019, 4 (07) : 463 - 478
  • [8] Light-Responsive Arylazopyrazole Gelators: From Organic to Aqueous Media and from Supramolecular to Dynamic Covalent Chemistry
    Chu, Chih-Wei
    Stricker, Lucas
    Kirse, Thomas M.
    Hayduk, Matthias
    Ravoo, Bart Jan
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (24) : 6131 - 6140
  • [9] Photolytic cleavage of 1-(2-nitrophenyl)ethyl ethers involves two parallel pathways and product release is rate-limited by decomposition of a common hemiacetal intermediate
    Corrie, JET
    Barth, A
    Munasinghe, VRN
    Trentham, DR
    Hutter, MC
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (28) : 8546 - 8554
  • [10] Reversible optical transcription of supramolecular chirality into molecular chirality
    de Jong, JJD
    Lucas, LN
    Kellogg, RM
    van Esch, JH
    Feringa, BL
    [J]. SCIENCE, 2004, 304 (5668) : 278 - 281
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