CsPbBr3 perovskite thin films by magnetron sputtering: The role of the substrate on texture and morphology

被引:5
作者
Calisi, Nicola [1 ,2 ]
Martinuzzi, Stefano Mauro [2 ,3 ]
Giaccherini, Andrea [2 ,3 ]
Innocenti, Massimo [2 ,3 ]
Mannini, Matteo [2 ,3 ]
Carla, Francesco [4 ]
Caporali, Stefano [1 ,2 ]
机构
[1] Univ Florence, Dept Ind Engn, DIEF, Via S Marta 3, I-50139 Florence, FI, Italy
[2] Natl Interuniv Consortium Mat Sci & Technol INSTM, Res Unit Firenze, Via G Giusti 9, I-50121 Florence, FI, Italy
[3] Univ Florence, Ugo Schiff Dept Chem, DICUS, Via Lastruccia 13, I-50019 Sesto Fiorentino, FI, Italy
[4] Diamond Light Source Ltd, Diamond House,Harwell Sci & Innovat Campus, Didcot OX11 0DE, Oxon, England
关键词
Perovskite; Thin film; Synchrotron radiation; Texture; Magnetron sputtering; LEAD;
D O I
10.1016/j.tsf.2023.140057
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Among the functional materials suitable for the realization of solar cells and light emission diodes (LEDs), perovskites, especially fully inorganic perovskites, are considered among the most promising. CsPbBr3 is the most studied due to its favorable band gap value and stability under mild atmospheric conditions: moisture and UV visible radiation exposure. Using this material, highly efficient thin film solar cells have been produced at the lab scale, and researchers aim to scale the process up to the industrial level.Here, ultrathin films of CsPbBr3 were obtained by magnetron sputtering, and the texture and morphology of the deposited films were evaluated as a function of their thickness and the substrate's nature. The obtained films are composed of highly textured structures of submicrometric crystals homogeneously distributed all over the surface. Finally, the texture decreases as the deposit thickness increases.
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页数:6
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