Enhanced energy storage efficiency and temperature stability of Li2CO3-assisted BST-based ceramics by optimizing B-site dopants

被引：7

作者：

Zhao, Hong ^{[1
]}

Xu, Dan ^{[1
]}

Duan, Xiaoyang ^{[1
]}

Zhou, Xinyuan ^{[1
]}

Jia, Wenjun ^{[1
]}

Zhao, Wenjie ^{[2
]}

机构：

[1] Harbin Univ Sci & Technol, Sch Sci, Harbin 150080, Peoples R China

[2] Harbin Univ Sci & Technol, Higher Educ Key Lab Measuring & Control Technol &, Harbin 150080, Peoples R China

来源：

CERAMICS INTERNATIONAL | 2023年 / 49卷 / 23期

基金：

中国国家自然科学基金;

关键词：

BST ceramics; Li2CO3; B-site dopants; Energy storage; Temperature stability; LEAD-FREE CERAMICS; ELECTRICAL-PROPERTIES; DIELECTRIC-PROPERTIES; PHASE-TRANSITION; DENSITY; RELAXOR; BEHAVIOR; CAPACITORS; PERFORMANCE; FILMS;

D O I：

10.1016/j.ceramint.2023.09.253

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

In this work, 5 wt%o Li2CO3-doped 0.88Ba0.8Sr0.2TiO3-0.12BiMeO3 (BST-BMe+5%oLi2CO3, Me = Al3+, Ga3+, Ta5+, and In3+) ceramics were fabricated using solid phase sintering approach. The impacts of different B-site Me ions on the crystalline structure, permittivity stability, energy density, and energy storage efficiency of these ceramics were studied. The XRD results revealed that the mixed tetragonal (T) and pseudo cubic (pC) phase structure was obtained for all the samples. The In/5%oLi2CO3 sample exhibits the optimal energy density of Wrec = 1.04 J/cm3 and the energy efficiency of eta = 96% at 170 kV/cm. Meanwhile, the sample shows outstanding temperature stability satisfying the EIA-X8R criteria, which is ascribed to the combined roles of defect dipoles and large lattice distortion. Li2CO3 plays a key role in reducing the sintering temperature, raising the breakdown strength, enhancing the relaxation characteristics, and improving the thermal stability of energy efficiency of the ceramics.

引用

页码：39134 / 39146

页数：13

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