Metal-organic framework-derived indium nanotubes for CO2 electroreduction to formate

被引：0

作者：

Hu, Jingyang ^{[1
,2
]}

Zhang, Jianling ^{[1
,2
]}

Tan, Zhonghao ^{[1
,2
]}

Wang, Sha ^{[1
]}

Yang, Yisen ^{[1
,2
]}

Zhao, Yingzhe ^{[1
,2
]}

Su, Zhuizhui ^{[1
,2
]}

Wang, Yanyue ^{[1
,2
]}

Tai, Jing ^{[3
]}

机构：

[1] Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci,Inst Chem, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China

[3] Chinese Acad Sci, Ctr Physicochem Anal & Measurement, Inst Chem, Beijing 100190, Peoples R China

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2023年 / 362卷

基金：

中国国家自然科学基金;

关键词：

Metal-organic framework; Indium; Nanotube; CO; 2; electroreduction; Formate; REDUCTION; ELECTROCATALYSIS; CONVERSION; CATALYSTS;

D O I：

10.1016/j.micromeso.2023.112781

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Electrochemical conversion of CO2 to chemicals is an appealing route to reduce carbon emission and achieve carbon neutrality. Indium (In) is a promising electrocatalyst for CO2-to-formate conversion due to its high selectivity to formate, but is still hindered by low current density and poor stability. In this work, we propose the construction of In nanotubes from MIL-68(In) metal-organic framework nanotubes by a electrolytic route, which is simple, rapid and low-cost. Benefiting from the nanotube morphology and abundant unsaturated coordination In sites, the as-synthesized In nanotubes exhibit high performance for the electrochemical CO2-to-formate conversion. The formate Faradaic efficiency can reach 98.6% at -1.2 V versus reversible hydrogen electrode by using 0.5 M KHCO3 aqueous solution as electrolyte in H-cell, with current density of 24.8 mA cm-2.

引用

页数：6

共 48 条

[1] Divergent Paths, Same Goal: A Pair-Electrosynthesis Tactic for Cost-Efficient and Exclusive Formate Production by Metal-Organic-Framework-Derived 2D Electrocatalysts [J].

Cao, Changsheng ;

Ma, Dong-Dong ;

Jia, Jingchun ;

Xu, Qiang ;

Wu, Xin-Tao ;

Zhu, Qi-Long .

ADVANCED MATERIALS, 2021, 33 (25)

[2] Metal-Organic Layers Leading to Atomically Thin Bismuthene for Efficient Carbon Dioxide Electroreduction to Liquid Fuel [J].

Cao, Changsheng ;

Ma, Dong-Dong ;

Gu, Jia-Fang ;

Xie, Xiuyuan ;

Zeng, Guang ;

Li, Xiaofang ;

Han, Shu-Guo ;

Zhu, Qi-Long ;

Wu, Xin-Tao ;

Xu, Qiang .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (35) :15014-15020

[3] Amination strategy to boost the CO2 electroreduction current density of M-N/C single-atom catalysts to the industrial application level [J].

Chen, Zhipeng ;

Zhang, Xinxin ;

Liu, Wei ;

Jiao, Mingyang ;

Mou, Kaiwen ;

Zhang, Xiangping ;

Liu, Licheng .

ENERGY & ENVIRONMENTAL SCIENCE, 2021, 14 (04) :2349-2356

[4] The nature of active sites for carbon dioxide electroreduction over oxide-derived copper catalysts [J].

Cheng, Dongfang ;

Zhao, Zhi-Jian ;

Zhang, Gong ;

Yang, Piaoping ;

Li, Lulu ;

Gao, Hui ;

Liu, Sihang ;

Chang, Xin ;

Chen, Sai ;

Wang, Tuo ;

Ozin, Geoffrey A. ;

Liu, Zhipan ;

Gong, Jinlong .

NATURE COMMUNICATIONS, 2021, 12 (01)

[5] Tin(IV) Sulfide Greatly Improves the Catalytic Performance of UiO-66 for Carbon Dioxide Cycloaddition [J].

Cheng, Xiuyan ;

Zhang, Bingxing ;

Shi, Jinbiao ;

Zhang, Jianling ;

Zheng, Lirong ;

Zhang, Jing ;

Shao, Dan ;

Tan, Xiuniang ;

Han, Buxing ;

Yang, Guanying .

CHEMCATCHEM, 2018, 10 (14) :2945-2948

[6] What would it take for renewably powered electrosynthesis to displace petrochemical processes? [J].

De Luna, Phil ;

Hahn, Christopher ;

Higgins, Drew ;

Jaffer, Shaffiq A. ;

Jaramillo, Thomas F. ;

Sargent, Edward H. .

SCIENCE, 2019, 364 (6438) :350-+

[7] Metal-Organic Framework-Derived Carbon Nanorods Encapsulating Bismuth Oxides for Rapid and Selective CO2 Electroreduction to Formate [J].

Deng, Peilin ;

Yang, Fan ;

Wang, Zhitong ;

Chen, Shenghua ;

Zhou, Yinzheng ;

Zaman, Shahid ;

Xia, Bao Yu .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (27) :10807-10813

[8] Boosting Electrochemical CO2 Reduction on Metal-Organic Frameworks via Ligand Doping [J].

Dou, Shuo ;

Song, Jiajia ;

Xi, Shibo ;

Du, Yonghua ;

Wang, Jiong ;

Huang, Zhen-Feng ;

Xu, Zhichuan J. ;

Wang, Xin .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (12) :4041-4045

[9] High-Curvature Transition-Metal Chalcogenide Nanostructures with a Pronounced Proximity Effect Enable Fast and Selective CO2 Electroreduction [J].

Gao, Fei-Yue ;

Hu, Shao-Jin ;

Zhang, Xiao-Long ;

Zheng, Ya-Rong ;

Wang, Hui-Juan ;

Niu, Zhuang-Zhuang ;

Yang, Peng-Peng ;

Bao, Rui-Cheng ;

Ma, Tao ;

Dang, Zheng ;

Guan, Yong ;

Zheng, Xu-Sheng ;

Zheng, Xiao ;

Zhu, Jun-Fa ;

Gao, Min-Rui ;

Yu, Shu-Hong .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (22) :8706-8712

[10] Structural defects on converted bismuth oxide nanotubes enable highly active electrocatalysis of carbon dioxide reduction [J].

Gong, Qiufang ;

Ding, Pan ;

Xu, Mingquan ;

Zhu, Xiaorong ;

Wang, Maoyu ;

Deng, Jun ;

Ma, Qing ;

Han, Na ;

Zhu, Yong ;

Lu, Jun ;

Feng, Zhenxing ;

Li, Yafei ;

Zhou, Wu ;

Li, Yanguang .

NATURE COMMUNICATIONS, 2019, 10 (1)

← 1 2 3 4 5 →