Benzoate-based thermally activated delayed fluorescence materials

被引：1

作者：

Zhang, Liang ^{[1
]}

Zhu, Wenjing ^{[1
]}

Gao, Kangkang ^{[1
]}

Wu, Yun ^{[1
]}

Lu, Yani ^{[1
]}

Shuai, Chao ^{[1
]}

Zhang, Penghui ^{[1
]}

Li, Huicheng ^{[1
]}

Chen, Chuan-Feng ^{[1
,2
,3
]}

机构：

[1] Longdong Univ, Coll Petrochem Engn, Qingyang 745000, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

RSC ADVANCES | 2023年 / 13卷 / 31期

关键词：

LIGHT-EMITTING-DIODES; PERFORMANCE; OLEDS; MOLECULES; EMITTERS;

D O I：

10.1039/d3ra03289b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Compounds PTZ-MBZ (methyl 3-(10H-phenothiazin-10-yl)benzoate) and DMAC-MBZ (methyl 3-(9,9-dimethylacridin-10(9H)-yl)benzoate) were conveniently synthesized, and they exhibited TADF properties with lifetimes of 0.80 and 2.17 mu s, respectively. The spatially separated highest occupied molecular orbital and lowest unoccupied molecular orbital resulted in a very small singlet-triplet energy gap of 0.0152 eV and 0.0640 eV, respectively. Thermally activated delayed fluorescence materials with short lifetime could be used as promising luminescent materials for organic light-emitting diodes.

引用

页码：21296 / 21299

页数：4

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