High surface area mesoporous carbon from black cumin (Nigella sativa) processing industry solid residues via single-stage K2CO3 assisted carbonization method: Production optimization, characterization and its some water pollutants removal and supercapacitor performance

被引:15
作者
Teymur, Yekbun Avsar [1 ]
Guzel, Fuat [2 ]
Inal, I. Isil Gurten [3 ]
机构
[1] Dicle Univ, Inst Nat & Appl Sci, Dept Chem, TR-21280 Diyarbakir, Turkiye
[2] Dicle Univ, Fac Educ, Dept Chem, TR-21280 Diyarbakir, Turkiye
[3] Ankara Univ, Fac Engn, Dept Chem Engn, TR-06100 Ankara, Turkiye
关键词
Black cumin; Activated carbon; Characterization; Sorption; Supercapacitor; CONVENTIONAL HEATING METHODS; PHOENIX-DACTYLIFERA L; ACTIVATED CARBON; METHYLENE-BLUE; CHEMICAL ACTIVATION; AQUEOUS-SOLUTION; KOH ACTIVATION; POROUS CARBON; SEWAGE-SLUDGE; WASTE TEA;
D O I
10.1016/j.diamond.2023.109815
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study, solid residues (BR) from the black cumin (Nigella sativa) processing industry, an abundant and sustainable raw material, were converted into high surface area mesoporous activated carbon (AC) under op-timum production conditions using a single-stage K2CO3 assisted carbonization method. The optimal AC (BRAC) which had the highest BET surface area (2211 m2/g), total pore volume (1.262 cm3/g), and mean pore diameter (2.8 nm) was achieved in the conditions of a K2CO3 impregnation ratio of 1:1, a carbonization temperature of 900 degrees C, and a carbonization period of 1 h. To test its adsorption performance from the aqueous phase, methylene blue dye, oxytetracycline antibiotic, and lead metal ions were selected as model water pollutants and found to be 714.3, 833.3, and 500.0 mg/g, respectively, at 25 degrees C Also, the electrode made of BRAC showed electrochemical capacitor performance with a high gravimetric capacitance (210 F/g) and cyclic stability (95 %).
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页数:14
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