Fundamental Understanding of Structural Reconstruction Behaviors in Oxygen Evolution Reaction Electrocatalysts

被引:138
作者
Zhong, Haoyin [1 ]
Zhang, Qi [1 ]
Yu, Junchen [1 ]
Zhang, Xin [1 ]
Wu, Chao [2 ]
Ma, Yifan [1 ]
An, Hang [1 ]
Wang, Hao [1 ]
Zhang, Jun [1 ]
Wang, Xiaopeng [1 ,2 ]
Xue, Junmin [1 ]
机构
[1] Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117575, Singapore
[2] Sichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Peoples R China
基金
新加坡国家研究基金会;
关键词
electrocatalysis; oxygen evolution reaction; structure-performance relationship; structural reconstruction; METAL-ORGANIC-FRAMEWORK; LATTICE OXYGEN; WATER OXIDATION; ACTIVE-SITES; SURFACE; PEROVSKITE; DISSOLUTION; CATALYSIS; REDOX; PERFORMANCE;
D O I
10.1002/aenm.202301391
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Transition metal-based oxyhydroxides (MOOH) derived from the irreversible structural reconstruction of precatalysts are often acknowledged as the real catalytic species for the oxygen evolution reaction (OER). Typically, the reconstruction-derived MOOH would exhibit superior OER activity compared to their directly synthesized counterparts, despite being fundamentally similar in chemistry. As such, structural reconstruction has emerged as a promising strategy to boost the catalytic activity of electrocatalysts. However, the in-depth understanding of the origin of the superior OER activity of reconstructed materials still remains ambiguous, which significantly hinders the further developments of highly efficient electrocatalysts based on structural reconstruction chemistry. In this review, a comprehensive overview of the structural reconstruction behaviors in the reported reconstruction-derived electrocatalysts is provided and the intrinsic chemical and structural origins of their high efficiency toward OER are unveiled. The fundamentals of structural reconstruction mechanisms, along with the recommended characterization techniques for the understanding of the dynamic structural reconstruction process and analyzing the structure of real catalytic species are also interpreted. Finally, in view of structural reconstruction chemistry, the potential perspectives to facilitate the design and synthesis of highly efficient and durable OER electrocatalyst are presented.
引用
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页数:25
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共 152 条
[1]   Reduced overpotentials for electrocatalytic water splitting over Fe- and Ni-modified BaTiO3 [J].
Artrith, Nongnuch ;
Sailuam, Wutthigrai ;
Limpijumnong, Sukit ;
Kolpak, Alexie M. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (42) :29561-29570
[2]   Double-atom catalysts as a molecular platform for heterogeneous oxygen evolution electrocatalysis [J].
Bai, Lichen ;
Hsu, Chia-Shuo ;
Alexander, Duncan T. L. ;
Chen, Hao Ming ;
Hu, Xile .
NATURE ENERGY, 2021, 6 (11) :1054-1066
[3]   Comparison of Fe-enhanced oxygen evolution electrocatalysis in amorphous and crystalline nickel oxides to evaluate the structural contribution [J].
Bak, Jumi ;
Yun, Tae Gyu ;
An, Ji-Sang ;
Bae, Hyung Bin ;
Chung, Sung-Yoon .
ENERGY & ENVIRONMENTAL SCIENCE, 2022, 15 (02) :610-620
[4]   Atomic-scale perturbation of oxygen octahedra via surface ion exchange in perovskite nickelates boosts water oxidation [J].
Bak, Jumi ;
Bae, Hyung Bin ;
Chung, Sung-Yoon .
NATURE COMMUNICATIONS, 2019, 10 (1)
[5]   Formation of Two-Dimensional Homologous Faults and Oxygen Electrocatalytic Activities in a Perovskite Nickelate [J].
Bak, Jumi ;
Bae, Hyung Bin ;
Kim, Jaehoon ;
Oh, Jihun ;
Chung, Sung-Yoon .
NANO LETTERS, 2017, 17 (05) :3126-3132
[6]   Electronic design criteria for O-O bond formation via metal-oxo complexes [J].
Betley, Theodore A. ;
Wu, Qin ;
Van Voorhis, Troy ;
Nocera, Daniel G. .
INORGANIC CHEMISTRY, 2008, 47 (06) :1849-1861
[7]   In situ reconstruction enhanced dual-site catalysis towards nitrate electroreduction to ammonia [J].
Cai, Jiahao ;
Qin, Shuaibo ;
Akram, Muhammad Awais ;
Hou, Xiangdie ;
Jin, Peng ;
Wang, Feng ;
Zhu, Botao ;
Li, Xiaohong ;
Feng, Lai .
JOURNAL OF MATERIALS CHEMISTRY A, 2022, 10 (23) :12669-12678
[8]   In situsurface reconstruction synthesis of a nickel oxide/nickel heterostructural film for efficient hydrogen evolution reaction [J].
Chen, Haixin ;
Ge, Dongqi ;
Chen, Junwei ;
Li, Ruchun ;
Zhang, Xiaofeng ;
Yu, Tongwen ;
Wang, Yi ;
Song, Shuqin .
CHEMICAL COMMUNICATIONS, 2020, 56 (72) :10529-10532
[9]   Recent Advances in the Understanding of the Surface Reconstruction of Oxygen Evolution Electrocatalysts and Materials Development [J].
Chen, Junwei ;
Chen, Haixin ;
Yu, Tongwen ;
Li, Ruchun ;
Wang, Yi ;
Shao, Zongping ;
Song, Shuqin .
ELECTROCHEMICAL ENERGY REVIEWS, 2021, 4 (03) :566-600
[10]   Constructing Air-Stable and Reconstruction-Inhibited Transition Metal Sulfide Catalysts via Tailoring Electron-Deficient Distribution for Water Oxidation [J].
Chen, Runzhe ;
Zhang, Zeyi ;
Wang, Zichen ;
Wu, Wei ;
Du, Shaowu ;
Zhu, Wangbin ;
Lv, Haifeng ;
Cheng, Niancai .
ACS CATALYSIS, 2022, 12 (21) :13234-13246