Enhanced energy storage properties of Ba0.85Ca0.15Zr0.1Ti0.9O3 ceramics doped with BiFeO3

被引:22
作者
Chen, S. Y. [1 ]
Liu, R. [1 ]
Zheng, Y. P. [2 ]
Shi, Y. J. [1 ]
Dang, S. T. [1 ]
Shi, Y. C. [1 ]
Yang, F. [1 ]
Li, J. H. [1 ]
He, L. F. [1 ]
Wu, S. J. [1 ]
Li, X. F. [1 ]
Hu, Y. C. [1 ]
Shang, J. [1 ]
Yin, S. Q. [1 ]
Wang, X. W. [1 ]
机构
[1] Henan Normal Univ, Sch Phys, Lab Funct Mat, Henan Key Lab Photovolta Mat, Xinxiang 453007, Peoples R China
[2] Sch Mat Sci & Engn, Harbin Inst Technol, Natl Key Lab Mat Behav & Evaluat Technol Space Env, Harbin 150001, Peoples R China
基金
中国国家自然科学基金;
关键词
Electrical performance; Energy storage performance; Ba0; 85Ca0; 15Zr0; 1Ti0; BiFeO3; DIELECTRIC-PROPERTIES; FERROELECTRIC PROPERTIES; RELAXOR BEHAVIOR; TEMPERATURE; BZT;
D O I
10.1016/j.jallcom.2022.168015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The structure and electrical properties of Ba0.85Ca0.15Zr0.1Ti0.9O3-xBiFeO3 ceramics (x = 0 %, 3 %, 8 % and 15 %) were investigated. The prepared samples show perovskite structure, and there is no detected second phase. The grain size of all ceramic samples doped with BiFeO3 is significantly reduced. The doped samples have obvious relaxation characteristics, showing obvious dispersion phase transition and frequency dispersion. The P-E curve becomes thin with the increase of doping amount, but it changes reversely under higher doping content. For sample with the doping amount of 8 %, a thin and long hysteresis loop is observed, and the sample has the best energy storage characteristics with the energy storage density of 0.57 J/cm3 and the energy storage efficiency of 91.3 %. This study provides a method to improve the energy storage density and efficiency of BCZT ceramics.(c) 2022 Elsevier B.V. All rights reserved.
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页数:7
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