Silver-catalyzed nitrosation and nitration of aromatic amides using NOBF4

被引：0

作者：

Li, Sa ^{[1
]}

Liu, Wentao ^{[2
]}

Xia, Xiao-Feng ^{[1
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Key Lab Synthet & Biol Colloids, Minist Educ, Wuxi 214122, Jiangsu, Peoples R China

[2] Ind & Informat Technol Dev Ctr Yinan Cty, Linyi 276300, Shandong, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 47期

基金：

中国国家自然科学基金;

关键词：

NITROSOARENES; HYDROLYSIS; CHEMISTRY; OXIDATION; ANILINES; NITRITE; AMINES; ARENES;

D O I：

10.1039/d3ob01729j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Divergent aromatic ring nitrosation and nitration of aromatic amides are reported using NOBF4 as the electrophile under silver-catalyzed conditions. The reactions proceed efficiently with a wide range of compatible functionalities providing ortho-position nitrosation products, deacylation nitrosation products, and nitration products from different tertiary and secondary aromatic amides.

引用

页码：9428 / 9432

页数：5