Enhanced electrochemical performance of CoMoO4 nanorods/reduced graphene oxide (rGO) as asymmetric supercapacitor devices

被引:11
作者
Nandagopal, T. [1 ]
Balaji, G. [1 ]
Vadivel, S. [2 ]
机构
[1] Paavai Engn Coll Autonomous, Dept Elect & Elect Engn, Namakkal 637018, Tamilnadu, India
[2] Saveetha Inst Med & Tech Sci SIMATS, Saveetha Sch Engn, Dept Phys, Chennai 602105, Tamil Nadu, India
关键词
CoMoO4; Hydrothermal; rGO; Supercapacitor energy storage device; ELECTRODE; CAPACITANCE; MECHANISM; ARRAYS; ANODE;
D O I
10.1016/j.est.2023.107710
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The efficiency of a supercapacitor depends heavily on the materials used to create its electrodes. Physicochemical properties have piqued interest in using transition metal molybdates as electrode materials in supercapacitors. Monodisperse CoMoO4 nanorods with a modest dimension (about 40-60 nm in width and 1.5-2 lim in length) were created on reduced graphene oxide (rGO) nanosheets were synthesized via a facile hydrothermal method. Hybrid CoMoO4@rGO electrodes have shown exceptional electrochemical properties, especially when compared to pure CoMoO4 in an alkaline electrolyte. In particular, the maximum specific capacitance of CoMoO4@rGO is 1425 Fg- 1 at a current density of 1Ag-1, while the greatest specific capacitance of CoMoO4 is 751 Fg- 1 at the same current density. Both the pure and hybrid electrodes show excellent rate capability and long-term cyclic stability, even at high current densities of 20 Ag-1. Also, at a current density of 20 Ag-1, the constructed asymmetric supercapacitor generated a maximum power density of 4.5 kWkg-1, and at a current density of 1 Ag-1, it generated a high energy density of 51.2 Whkg-1. Based on their promising electrochemical performance, the hierarchical CoMoO4@rGO nanocomposites were discovered to provide for a promising electrode material in the creation of highly effective supercapacitors for power storage.
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页数:8
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