Ionic liquids in cationic polymerization: A review

被引：10

作者：

Berezianko, Ivan A. ^{[1
]}

Kostjuk, Sergei, V ^{[1
,2
,3
]}

机构：

[1] Belarusian State Univ, Res Inst Phys Chem Problems, 14 Leningradskaya st, Minsk 220006, BELARUS

[2] Belarusian State Univ, Dept Chem, 14 Leningradskaya st, Minsk 220006, BELARUS

[3] Sechenov First Moscow State Med Univ, Inst Regenerat Med, Moscow 119991, Russia

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2024年 / 397卷

关键词：

Cationic polymerization; Polyisobutylene; Polystyrene; Ionic liquids; Acidic ionic liquids; Catalysis; RING-OPENING POLYMERIZATION; TRANSFER RADICAL POLYMERIZATION; RECYCLABLE REACTION MEDIUM; ANIONIC-POLYMERIZATION; MEDIATED SYNTHESIS; CHAIN TRANSFER; 1-BUTYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE; METHYL-METHACRYLATE; RAFT POLYMERIZATION; CATALYZED SYNTHESIS;

D O I：

10.1016/j.molliq.2024.124037

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This article reviews a progress reached in application of neutral and acidic ionic liquids (ILs) in cationic polymerization processes. The whole subject was divided into two parts: (i) neutral ILs as solvents for polymerization and (ii) acidic ILs as polymerization catalysts. Detailed examination of literature since the beginning of 1990s to 2023 year revealed the diversity of roles which ionic liquids could play in promotion of cationic polymerization. Special focus here is laid on the discussion of benefits, which ionic liquids are bringing into the proceeding of cationic polymerization. The synthesis and properties of (co)polymers from styrene and its derivatives, isobutylene, vinyl ethers and conjugated 1,3-dienes were discussed in this review in details. Thorough literature review shows that despite reaching a quite substantial research progress, sustainable development concept is still requiring "green" approaches toward polymers synthesis.

引用

页数：17

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