1,3-Butadiene Dicarbofunctionalization Enabled by the Dual Role of Diaryl Ketone in Photo-HAT/Chromium Catalysis

被引：11
作者：
Hu, Qiang [1 ]
Song, Shuo [1 ]
Zeng, Tianlong [1 ]
Wang, Lele [1 ]
Li, Zhongxian [1 ]
Wu, Jiacheng [1 ]
Zhu, Jun [1 ]
机构：
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China
来源：
ORGANIC LETTERS | 2024年 / 26卷 / 08期
基金：
中国国家自然科学基金;
关键词：
CHROMIUM; HYDROCARBONS; ACTIVATION; 1,3-DIENES; 1,4-DIOLS; ALDEHYDES;
D O I：
10.1021/acs.orglett.3c04205
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We report a three-component Nozaki-Hiyama-Kishi type reaction of 1,3-dioxolane, 1,3-butadienes, and aldehydes to access masked aldehyde-incorporated homoallylic alcohols, facilitated by photo-hydrogen atom transfer (HAT)/chromium dual catalysis. The diaryl ketone serves dual roles both in the HAT process and in facilitating the turnover of the chromium catalyst. A range of functional groups are tolerated owing to the mild conditions. Both aromatic and aliphatic aldehydes are suitable substrates for coupling with several 1,3-butadienes and 1,3-dioxolane.
引用
收藏
页码：1550 / 1555
页数：6
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