Biodiesel production from spirulina algae oil over cobalt microsphere through esterification reaction

被引:3
作者
Taherinia, Zahra [1 ]
Ghorbani-Choghamarani, Arash [2 ]
Lemraski, Ensieh Ghasemian [1 ]
机构
[1] Ilam Univ, Fac Sci, Dept Chem, Ilam, Iran
[2] Bu Ali Sina Univ, Fac Chem, Dept Organ Chem, Hamadan 6517838683, Iran
关键词
Spirulina algae oil; Microsphere cobalt; Solvothermal method; Dipyridin-2-ylmethanone; METAL-ORGANIC-FRAMEWORK; RENEWABLE ENERGY; CO2; FIXATION; MICROALGAE; TRANSESTERIFICATION; EFFICIENT; BIOFUELS; CATALYST; CARBON; OPTIMIZATION;
D O I
10.1016/j.mtsust.2023.100647
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study displays the production and conformance of cobalt microsphere as a catalyst in the esterification reaction for biodiesel production from spirulina algae oil. The porous microsphere was successfully synthesized via a simple solvothermal method and evaluated using EDX, XRD, FE-SEM, TGA, CO2-TPD, and BET. The resulting microsphere cobalt has a surface area of 150.83 m(2)/g and a total pore volume of 35.33 cm(3)/g. The optimal reaction conditions for the esterification of spirulina algae oil over the cobalt microsphere were: 60 degrees C, a molar ratio of 7:1 for methanol: spirulina algae oil, and 240 min to achieve 95 % yield of corresponding product. Also, biodiesel samples comply with the ASTM standards. The chemical composition of spirulina oil was analyzed by GC-Mass analysis. The cobalt microsphere offers various benefits such as stability (chemical/physical), simple catalyst separation, and the production of high-quality biodiesel.
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页数:10
相关论文
共 65 条
[1]   Tailoring the surface area and the acid-base properties of ZrO2 for biodiesel production from Nannochloropsis sp. [J].
Abd Rahman, Nurul Jannah ;
Ramli, Anita ;
Jumbri, Khairulazhar ;
Uemura, Yoshimitsu .
SCIENTIFIC REPORTS, 2019, 9 (1)
[2]   A review of biomass-derived heterogeneous catalyst for a sustainable biodiesel production [J].
Abdullah, Sharifah Hanis Yasmin Sayid ;
Hanapi, Nur Hanis Mohamad ;
Azid, Azman ;
Umar, Roslan ;
Juahira, Hafizan ;
Khatoon, Helena ;
Endut, Azizah .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2017, 70 :1040-1051
[3]   Sustainable development of renewable energy integrated power sector: Trends, environmental impacts, and recent challenges [J].
Al-Shetwi, Ali Q. .
SCIENCE OF THE TOTAL ENVIRONMENT, 2022, 822
[4]   Biofuels and sustainability in Africa [J].
Amigun, Bamikole ;
Musango, Josephine Kaviti ;
Stafford, William .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2011, 15 (02) :1360-1372
[5]   Algal Photosynthesis as the Primary Driver for a Sustainable Development in Energy, Feed, and Food Production [J].
Anemaet, Ida G. ;
Bekker, Martijn ;
Hellingwerf, Klaas J. .
MARINE BIOTECHNOLOGY, 2010, 12 (06) :619-629
[6]  
[Anonymous], 2008, GLOSS SOIL SCI TERMS
[7]   Recent advancement and strategy on bio-hydrogen production from photosynthetic microalgae [J].
Anwar, Muhammad ;
Lou, Sulin ;
Chen, Liu ;
Li, Hui ;
Hu, Zhangli .
BIORESOURCE TECHNOLOGY, 2019, 292
[8]   Critical review on the current scenario and significance of crude glycerol resulting from biodiesel industry towards more sustainable renewable energy industry [J].
Ayoub, Muhammad ;
Abdullah, Ahmad Zuhairi .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2012, 16 (05) :2671-2686
[9]  
Bajpai D., 2006, J OLEO SCI, V55, P487, DOI [10.5650/jos.55.487, DOI 10.5650/JOS.55.487]
[10]   Energy security and climate change concerns: Triggers for energy policy change in the United States? [J].
Bang, Guri .
ENERGY POLICY, 2010, 38 (04) :1645-1653