Recent advances in the selective semi-hydrogenation of alkyne to (E)-olefins

被引：5
作者：
Sk, Motahar [1 ]
Haldar, Shuvojit [1 ]
Bera, Sourajit [1 ]
Banerjee, Debasis [1 ]
机构：
[1] Indian Inst Technol Roorkee, Dept Chem, Lab Catalysis & Organ Synth, Roorkee 247667, Uttarakhand, India
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 12期
关键词：
CATALYZED STEREODIVERGENT SEMIHYDROGENATION; STEREOSELECTIVE-SYNTHESIS; TRANSFER HYDROGENATION; TRANS-HYDROGENATION; REDUCTION; EFFICIENT; POINT; STORY; H2O;
D O I：
10.1039/d3cc05395d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Considering the potential importance and upsurge in demand, the selective semi-hydrogenation of alkynes to (E)-olefins has attracted significant interest. This article highlights the recent advances in newer technologies and important methodologies directed to (E)-olefins from alkynes developed from 2015 to 2023. Notable features summarised include the catalyst or ligand design and control of product selectivity based on precious and nonprecious metal catalysts for semi-hydrogenation to (E)-olefins. Mechanistic studies for various catalytic transformations, including synthetic application to bioactive compounds, are summarised.
引用
收藏
页码：1517 / 1533
页数：17
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