Formation of Xenon Hydrate from a Vapor-Gas Medium

被引:0
|
作者
Ninenko, S. I. [1 ]
Zhovnerchuk, E. V. [2 ,3 ]
机构
[1] Russian Acad Sci, Vereshchagin Inst High Pressure Phys, Moscow 108840, Russia
[2] Izmerov Inst Occupat Med, Moscow 105275, Russia
[3] Fed Med Biol Agcy, Acad Postgrad Educ, Moscow 125371, Russia
关键词
xenon hydrate; hydrate formation; xenon clathrate;
D O I
10.1134/S0036024423060225
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Special two-chamber setups are used to study the formation of xenon hydrates from a vapor-gas medium, depending on the volume of the chamber. The effect different parameters have on the growth of hydrates and the degree of saturation is studied. Hydrate growth conditions with saturation indices close to ideal are determined. Based on the experimental data, an estimate is made of the size of the crystalline hydrate nucleus (minimum size, 10-15 mu m). It is established that for the emergence of such a nucleus from a vapor-gas medium, the required amount of steam at a temperature of 5 degrees C is contained in a sphere 1 cm in diameter. Conditions are determined for the growth of a hydrate with saturation close to theoretical from a vapor-gas medium. It is shown that the rate of hydrate formation in a vapor-gas medium is several orders of magnitude higher than the one for liquid water. Raising the initial temperature of the vapor-gas medium increases both the rate of hydrate formation and the proportion of such hydrate.
引用
收藏
页码:1148 / 1151
页数:4
相关论文
共 50 条
  • [1] Formation of Xenon Hydrate from a Vapor–Gas Medium
    S. I. Ninenko
    E. V. Zhovnerchuk
    Russian Journal of Physical Chemistry A, 2023, 97 : 1148 - 1151
  • [2] CONDITIONS OF MIST FORMATION IN MIXTURES VAPOR-GAS
    GOTZ, R
    PRZEMYSL CHEMICZNY, 1977, 56 (12): : 630 - 633
  • [3] Condensation from a vapor-gas mixture
    Kryukov A.P.
    Levashov V.Yu.
    Pavlyukevich N.V.
    Journal of Engineering Physics and Thermophysics, 2010, 83 (04) : 679 - 687
  • [4] Vapor Condensation from Vapor-gas Mixtures.
    Lekaje, W.M.
    Kusnezow, Ju.P.
    Mjagkow, L.W.
    Chemische Technik (Leipzig), 1981, 33 (04): : 179 - 182
  • [5] Numerical simulation of water droplet evaporation into vapor-gas medium
    Levashov, V. Yu.
    Kryukov, A. P.
    COLLOID JOURNAL, 2017, 79 (05) : 647 - 653
  • [6] Gas hydrate formation in porous medium
    Makogon, Y
    NGH '96 - 2ND INTERNATIONAL CONFERENCE ON NATURAL GAS HYDRATES, PROCEEDINGS, 1996, : 275 - 289
  • [7] SCREEN VAPOR-GAS SEPARATOR
    MAKSIMOV, NP
    KHIMICHESKAYA PROMYSHLENNOST, 1980, (09): : 558 - 558
  • [8] EVAPORATION IN A VAPOR-GAS MIXTURE
    PAO, YP
    JOURNAL OF CHEMICAL PHYSICS, 1973, 59 (12): : 6688 - 6689
  • [9] Film condensation from a dusty vapor-gas mixture
    Golubev, VG
    Brener, AM
    THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2002, 36 (02) : 123 - 127
  • [10] CONDENSATION OF VAPOR FROM A VAPOR-GAS MIXTURE AT A VERTICAL SURFACE.
    Volkov, Yu.A.
    Nikitin, V.M.
    Shkola, V.V.
    Power engineering New York, 1984, 22 (01): : 70 - 76