Effect of Quaternary Ammonium Gemini Surfactant Solution on the Rate Constant of the Ninhydrin-Lysine Reaction

被引:20
|
作者
Kumar, Dileep [4 ,5 ]
Khan, Javed Masood [1 ]
Posa, Mihalj [6 ]
Pulikkal, Ajmal Koya [2 ]
Saha, Bidyut [3 ]
Bhattarai, Ajaya [7 ]
机构
[1] King Saud Univ, Coll Food & Agr Sci, Dept Food Sci & Nutr, Riyadh 11451, Saudi Arabia
[2] Natl Inst Technol Mizoram, Dept Chem, Aizawl 796012, Mizoram, India
[3] Univ Burdwan, Dept Chem, Burdwan 713104, W Bengal, India
[4] Van Lang Univ, Inst Computat Sci & Artificial Intelligence, Lab Chem Computat & Modeling, Ho Chi Minh City 70000, Vietnam
[5] Van Lang Univ, Fac Appl Technol, Sch Technol, Ho Chi Minh City 70000, Vietnam
[6] Univ Novi Sad, Med Fac, Dept Pharm, Novi Sad 21000, Serbia
[7] Tribhuvan Univ, Dept Chem, MMAMC, Biratnagar 56613, Nepal
关键词
SPACER CHAIN-LENGTH; AGGREGATION BEHAVIOR; MIXED MICELLIZATION; MICELLAR; KINETICS; SALT; ACID; ADSORPTION; ADDITIVES; CHEMISTRY;
D O I
10.1021/acs.iecr.3c02499
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The effect of solutions of double-chained quaternary ammonium gemini surfactants (16-s-16, s = 4-6) was characterized on the rate constant of the ninhydrin (nin) and lysine (Lys) reaction using a ultraviolet-visible (UV-vis) spectrophotometer. Rate constant (k(psi)) values were obtained at different geminis. However, k(psi) values obtained at several geminis were displayed in the form of the k(psi)-[gemini] rate profile, and the quantitative estimation of these results was elucidated employing a model of micellar catalysis referred to as pseudophase. The role of other experimental ingredients such as nin, Lys, pH, and temperature (T) was examined in geminis, and k(psi) values as a function of these parameters were determined. Data treatment confirms a fractional order in [nin] and a unity order in [Lys]. Using conductometric evaluation, the critical micellar concentration (cmc) of pure double-chained gemini surfactants (16-6-16, 16-5-16, and 16-4-16) and presence of nin and Lys were recorded. Results of the present experimental value were used to determine micellar binding constants (K-A for Lys and K-B for nin). The binding constants and second-order rate (k(m)) affect the solvent properties at the micellar surface and hence are taken into consideration and discussed.
引用
收藏
页码:15897 / 15906
页数:10
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